Carbon-Carbon Formation via Ni-Catalyzed Suzuki-Miyaura Coupling through C-CN Bond Cleavage of Aryl Nitrile

被引：112
|
作者：
Yu, Da-Gang
Yu, Miao
Guan, Bing-Tao
Li, Bi-Jie
Zheng, Yang
Wu, Zhen-Hua
Shi, Zhang-Jie [1 ]
机构：
[1] Peking Univ, BNLMS, Beijing 100871, Peoples R China
来源：
ORGANIC LETTERS | 2009年 / 11卷 / 15期
关键词：
ARYLBORONIC ACIDS; INTRAMOLECULAR ARYLCYANATION; UNSYMMETRICAL BIARYLS; GRIGNARD-REAGENTS; O ACTIVATION; NICKEL; CHLORIDES; COMPLEXES; ETHERS; FUNCTIONALIZATION;
D O I：
10.1021/ol901217m
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Suzuki-Miyaura coupling of aryl nitriles with aryl/alkenyl boronic esters is reported. With this method, the cyano group could be applied as a protecting group of arenes and finally as a leaving group to further construct polyaryl scaffolds.
引用
收藏
页码：3374 / 3377
页数：4
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