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2-Methyltelluro-N-phenylbenzamide
被引:1
作者:
Gable, RW
[1
]
Laws, MJ
[1
]
Schiesser, CH
[1
]
机构:
[1] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia
关键词:
D O I:
10.1107/S010827019901118X
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The title tellurium compound, C14H13NOTe, is isostructural with the selenium analogue, 2-methylseleno-N-phenylbenzamide [Fong, Gable & Schiesser (1996). Acta Cryst. C52, I886-1889], having a Te ... O separation of 2.835(2)Angstrom. Steric repulsions between the ortho-H atom on the N-phenyl ring and the amide-O atom result in asymmetry in the bond angles around the junction C atom of the N-phenyl ring, while the angles around the N and amide C are influenced by the Te ... O interaction. The amide-N atom is involved in hydrogen bonding with the O atom of an adjacent molecule, forming zigzag chains that lie along the a axis.
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页码:2100 / 2102
页数:3
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