2-Methyltelluro-N-phenylbenzamide

被引：1
|
作者：
Gable, RW [1 ]
Laws, MJ [1 ]
Schiesser, CH [1 ]
机构：
[1] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷
关键词：
D O I：
10.1107/S010827019901118X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title tellurium compound, C14H13NOTe, is isostructural with the selenium analogue, 2-methylseleno-N-phenylbenzamide [Fong, Gable & Schiesser (1996). Acta Cryst. C52, I886-1889], having a Te ... O separation of 2.835(2)Angstrom. Steric repulsions between the ortho-H atom on the N-phenyl ring and the amide-O atom result in asymmetry in the bond angles around the junction C atom of the N-phenyl ring, while the angles around the N and amide C are influenced by the Te ... O interaction. The amide-N atom is involved in hydrogen bonding with the O atom of an adjacent molecule, forming zigzag chains that lie along the a axis.
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收藏
页码：2100 / 2102
页数：3
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