Miniemulsion polymerization

被引：902

作者：

Asua, JM ^{[1
]}

机构：

[1] Univ Basque Country, Inst Polymer Mat POLYMAT, Fac Ciencias Quim, Apdo 1072, Donostia San Sebastian 20080, Spain

[2] Univ Basque Country, Fac Ciencias Quim, Grp Ingn Quin, Donostia San Sebastian 20080, Spain

来源：

PROGRESS IN POLYMER SCIENCE | 2002年 / 27卷 / 07期

关键词：

miniemulsion polymerization; costabilizer; Ostwald ripening; droplet nucleation; high solids low viscosity latexes; controlled radical polymerization; catalytic polymerization; encapsulation; hydrophobic latexes; hybrid polymer particles; continuous reactors;

D O I：

10.1016/S0079-6700(02)00010-2

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Miniemulsion polymerization has recently exploded in terms of publications and the development of a wide range of useful polymer materials only accessible through this polymerization technique. In the first part of this article., the fundamental aspects involved in the preparation and polymerization of monomer miniemulsions are reviewed. The second part deals with the application of miniemulsion polymerization for the production of high solids low viscosity latexes, dispersion of polymers of well defined microstructure through controlled radical polymerization, use of catalytic polymerization in aqueous media, encapsulation of inorganic solids, incorporation of hydrophobic monomers, preparation of hybrid polymer particles, implementation of anionic and step polymerization in aqueous dispersed media, and process intensification by using continuous reactors. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1283 / 1346

页数：64

共 288 条

[41] Enhanced droplet nucleation in styrene miniemulsion polymerization. 3. Effect of shear in miniemulsions that use cetyl alcohol as the cosurfactant [J].