Aqueous phase catalytic hydrodechlorination of 4-chlorophenol over palladium deposited on reduced graphene oxide

被引:24
作者
Deng, Hongying [1 ]
Fan, Guangyin [1 ,2 ]
Wang, Chenyu [2 ]
Zhang, Lei [3 ]
机构
[1] China West Normal Univ, Coll Chem & Chem Ind, Chem Synth & Pollut Control Key Lab Sichuan Prov, Nanchong 637009, Peoples R China
[2] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA
[3] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China
基金
中国国家自然科学基金;
关键词
Palladium; Graphene; Hydrodechlorination; 4-Chlorophenol; CCL2F2; CFC-12; SUPPORTED CATALYSTS; SELECTIVE HYDROGENOLYSIS; ACTIVATED CARBON; CH2F2; HFC-32; PD; DEACTIVATION; CHLOROBENZENE; NANOCATALYSTS; TEMPERATURE;
D O I
10.1016/j.catcom.2013.12.025
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Palladium/reduced graphene oxide nanocomposites (Pd/RGO) are synthesized through the impregnation of polyvinyl-pyrrolidone-stabilized palladium nanoparticles on the surface of RGO sheets prepared from the reduction of graphene oxide in the presence of hydrogen gas. The Pd/RGO nanocomposites exhibited excellent catalytic property for the hydrodechlorination of 4-chlorophenol. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:219 / 223
页数:5
相关论文
共 31 条
[1]   Poisoning and deactivation of palladium catalysts [J].
Albers, P ;
Pietsch, J ;
Parker, SF .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 173 (1-2) :275-286
[2]   Influence of the reaction conditions and catalytic properties on the liquid-phase hydrodechlorination of chlorobenzene over palladium-supported catalysts:: Activity and deactivation [J].
Aramendía, MA ;
Boráu, V ;
García, IM ;
Jiménez, C ;
Lafont, F ;
Marinas, A ;
Marinas, JM ;
Urbano, FJ .
JOURNAL OF CATALYSIS, 1999, 187 (02) :392-399
[3]   Effect of chlorine released during hydrodechlorination of chlorobenzene over Pd, Pt and Rh supported catalysts [J].
Benitez, JL ;
Del Angel, G .
REACTION KINETICS AND CATALYSIS LETTERS, 2000, 70 (01) :67-72
[4]   Controlled Synthesis of PtRu/Graphene Nanocatalysts with Enhanced Methanol Oxidation Activity for Fuel Cells [J].
Cong, Huai-Ping ;
Ren, Xiao-Chen ;
Yu, Shu-Hong .
CHEMCATCHEM, 2012, 4 (10) :1555-1559
[5]   CONVERSION UNDER HYDROGEN OF DICHLORODIFLUOROMETHANE OVER SUPPORTED PALLADIUM CATALYSTS [J].
COQ, B ;
COGNION, JM ;
FIGUERAS, F ;
TOURNIGANT, D .
JOURNAL OF CATALYSIS, 1993, 141 (01) :21-33
[6]   Kinetics of the hydrodechlorination of 4-chlorophenol in water using Pd, Pt, and Rh/Al2O3 catalysts [J].
Diaz, Elena ;
Casas, Jose A. ;
Mohedano, Angel F. ;
Calvo, Luisa ;
Gilarranz, Miguel A. ;
Rodriguez, Juan J. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (11) :3840-3846
[7]   Comparison of activated carbon-supported Pd and Rh catalysts for aqueous-phase hydrodechlorination [J].
Diaz, Elena ;
Mohedano, Angel F. ;
Casas, Jose A. ;
Calvo, Luisa ;
Gilarranz, Miguel A. ;
Rodriguez, Juan J. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 106 (3-4) :469-475
[8]   High-surface area graphites as supports for hydrodechlorination catalysts: Tuning support surface chemistry for an optimal performance [J].
Diaz, Eva ;
Ordonez, Salvador ;
Bueres, Ruben F. ;
Asedegbega-Nieto, Esther ;
Sastre, Herminio .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 99 (1-2) :181-190
[9]   Facile synthesis of highly conductive polyaniline/graphite nanocomposites [J].
Du, XS ;
Xiao, M ;
Meng, YZ .
EUROPEAN POLYMER JOURNAL, 2004, 40 (07) :1489-1493
[10]   Reduced graphene oxide as a catalyst for hydrogenation of nitrobenzene at room temperature [J].
Gao, Yongjun ;
Ma, Ding ;
Wang, Chunlei ;
Guan, Jing ;
Bao, Xinhe .
CHEMICAL COMMUNICATIONS, 2011, 47 (08) :2432-2434