The first X-ray structurally characterized M3L2 cage-like complex with tetrahedral metal centres and its encapsulation of a neutral guest molecule

被引:184
作者
Liu, HK
Sun, WY [1 ]
Ma, DJ
Yu, KB
Tang, WX
机构
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Chinese Acad Sci, Anal Ctr, Chengdu 610041, Peoples R China
关键词
D O I
10.1039/b000259n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first X-ray structurally characterized M3L2 cage-like complex with tetrahedral metal centres [Zn-3(tib)(2)- (OAc)(6)]. xH(2)O [tib = 1,3,5-tris(imidazol-1-ylmethyl)benzene, x approximate to 4] obtained by reaction of zinc(ii) acetate with the tripodal ligand tib exhibits guest inclusion properties of neutral molecule such as synthetic camphor in aqueous solution.
引用
收藏
页码:591 / 592
页数:2
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