Mass transport by an oscillatory electroosmotic flow of power-law fluids in hydrophobic slit microchannels

In this work, we study the hydrodynamics, concentration field, and mass transport of species due to an oscillatory electroosmotic flow that obeys a power law. An additional aspect that is considered in the analysis corresponds to the effect of the slippage condition at the walls of the microchannel. The governing equations that describe the involved phenomena are the following: equation of Poisson-Boltzmann for the electrical potential in the electric double layer, the momentum equation, and the species transport equation. These equations were simplified with the aid of the lubrication theory and were numerically solved by using a conventional finite difference scheme. Our results suggest that, under the slippage effects, the best conditions can be promoted for the mass transport of species for different values of the Schmidt number and Womersley numbers less than unity, and even it is maximized up to two orders of magnitude when Wo>1. In the analysis, the cross-over phenomenon appears for the mass transport for different species and it is identified for both Newtonian and non-Newtonian fluids. For shear-thinning fluids with slippage at the microchannel walls, the cross-over phenomenon occurs, and the species with less diffusivity can be transported up to ten times faster in comparison with Newtonian fluids when the no-slip effect is considered.