Polyethylene/Aluminum Nanocomposites: Improvement of Dielectric Strength by Nanoparticle Surface Modification

The effect of the surface modification with a silane coupling agent (octyl-trimethoxysilane) of aluminum (Al) nanoparticles on the dielectric breakdown behaviors of polyethylene (PE)/Al nanocomposites was investigated in comparison of the influence of the improvement of the interfacial adhesion between Al nanoparticles and PE using a compatibilizer (maleic anhydride grafted polyethylene). It was found that when compared with the other modification approaches, the surface-treated Al nanofiller with the silane coupling agent makes it possible for the PE/Al nanocomposites to still keep the relatively higher breakdown strength even in the higher Al loading level above 14 vol%, which can be understood in terms of the better interfacial adhesion between the surface-treated particle dispersion and the matrix. The combined effects of the Al nanoparticles on the different factors which influence the dielectric breakdown processes in polymer matrix such as microstructure, conductivity, and crystallinity of the nanocomposites were discussed in detail. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 113: 35773584,2009