Static and dynamic light-scattering studies on micellar solutions of alkyldimethylbenzylammonium chlorides

Static (SLS) and dynamic (DLS) light-scattering techniques were applied to the study of the aggregation of dodecyl- (C(12)DBACI), tetradecyl- (C(14)DBACI), and hexadecyldimethylbenzylammonium (C(16)DBACI) chlorides in water and in 0.01 and 0.05 m NaCl aqueous solutions at 25 degreesC. Results of SLS measurements yielded critical micelle concentration (cmc) values for aqueous and NaCl solutions. The aggregation numbers of the micelles for the homologous surfactants are low but increase with chain length and ionic strength of the solution. Various patterns of changes of the diffusion coefficient, D, as a function of chain length, molality, and with ionic strength were found for the studied surfactants. Transformations in the structure of micelles of C(14)DBACI in 0.01 m NaCl occur at a concentration of surfactant of about 0.01 m. Such transformations, presumably due to rodlike structure, are the more extensive the higher the concentration of NaCl. The concentration of C(16)DBACI in 0.05 m NaCl covers the range where already repulsive interactions between micelles occur, as judged by the strongly negative slope of the D versus molality plot. To provide additional information on the suggested transformations, complementary viscosity measurements for C(14)DBACI in 0.01 m of NaCl have been performed. (C) 2004 Elsevier Inc. All rights reserved.