The supramolecular chemistry of organoplatinum complexes containing amide or alcohol functional groups

被引：6
|
作者：
Abo-Amer, Anwar [1 ,2 ]
Boyle, Paul D. [2 ]
Puddephatt, Richard J. [2 ]
机构：
[1] Al Al Bayt Univ, Dept Chem, Al Mafraq, Jordan
[2] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 770卷
基金：
加拿大自然科学与工程研究理事会;
关键词：
Supramolecular; Polymer; Hydrogen bond; Platinum; Oxidative addition; OXIDATIVE ADDITION; COORDINATION POLYMER; CARBOXYLIC-ACID; LIGANDS; SOLVENT;
D O I：
10.1016/j.jorganchem.2014.08.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The oxidative addition of alkyl bromides, RBr, to the dimethylplatinum(II) complex [PtMe2(bpox)], 1, bpox = 2,5-bis(2-pyridyl)-1,3,4-oxadiazole gave the corresponding organoplatinum(IV) complexes [PtBrMe2(R)(bpox)], R = CH2-4-C6H4C(=O)NHCH2Ph, 2; R = CH2-4-C6H4C(=O)NH-4-C6H4-t-Bu, 3; R = CH2-4-C6H4C(=O)NH-3,5-C6H3-t-Bu-2, 4; R = CH2-2-C6H4CH2OH, 5, which contain amide or alcohol functional groups. Several of these complexes form supramolecular polymers in the solid state through intermolecular hydrogen bonding. In complex 2 there is complementary hydrogen bonding between amide groups, while in complexes 3 and 5 the hydrogen bonding involves the oxygen atom of the bpox ligand as acceptor. (C) 2014 Elsevier B. V. All rights reserved.
引用
收藏
页码：79 / 84
页数：6
相关论文
共 50 条
  • [1] Organoplatinum(IV) complexes with functional alkyl groups and their use in supramolecular chemistry1
    Au, Richard H. W.
    Findlay-Shirras, Lisa J.
    Woody, Neil M.
    Jennings, Michael C.
    Puddephatt, Richard J.
    CANADIAN JOURNAL OF CHEMISTRY, 2009, 87 (07) : 904 - 916
  • [2] Supramolecular Organoplatinum(IV) Chemistry: Sequential Introduction of Amide Hydrogen Bonding Groups
    Au, Richard H. W.
    Jennings, Michael C.
    Puddephatt, Richard J.
    ORGANOMETALLICS, 2009, 28 (13) : 3754 - 3762
  • [3] Organoplatinum(IV) Complexes with Amide Groups: Supramolecular Structure as a Function of Ligand Flexibility
    Au, Richard H. W.
    Jennings, Michael C.
    Puddephatt, Richard J.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (11) : 1526 - 1534
  • [4] Reactivity of organoplatinum complexes containing appended alcohol functional groups: Activation of dioxygen and hydrogen peroxide
    Thompson, Kyle A.
    Kadwell, Connor
    Boyle, Paul D.
    Puddephatt, Richard J.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 829 : 22 - 30
  • [5] Investigation of the Amide Linkages on Cooperative Supramolecular Polymerization of Organoplatinum(II) Complexes
    Gui, Mingliang
    Han, Yifei
    Zhong, Hua
    Liao, Rui
    Wang, Feng
    MOLECULES, 2021, 26 (09):
  • [6] Supramolecular chemistry of organoplatinum(IV) complexes: A syndiotactic polymer with uracil substituents
    Nieradko, Michael J.
    Puddephatt, Richard J.
    JOURNAL OF CHEMICAL RESEARCH, 2022, 46 (04)
  • [7] Organoplatinum complexes with an ester substituted bipyridine ligand: Oxidative addition and supramolecular chemistry
    Safa, Muhieddine
    Puddephatt, Richard J.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 724 : 7 - 16
  • [8] Supramolecular Chemistry of Organoplatinum(IV) Complexes Bearing Ligands with Remote Carboxylic Acid Substituents
    Abo-Amer, Anwar
    Puddephatt, Richard J.
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2014, 24 (01) : 114 - 120
  • [9] Supramolecular Chemistry of Organoplatinum(IV) Complexes Bearing Ligands with Remote Carboxylic Acid Substituents
    Anwar Abo-Amer
    Richard J. Puddephatt
    Journal of Inorganic and Organometallic Polymers and Materials, 2014, 24 : 114 - 120
  • [10] Synthesis and properties of cobalt(III) complexes of tripodal ligands containing amide functional groups
    Angus, PM
    Elliott, AJ
    Sargeson, AM
    Willis, AC
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (07): : 1131 - 1136
12345