A UV-prepared linear polymer electrolyte membrane for dye-sensitized solar cells

被引：62

作者：

Imperiyka, M. ^{[1
]}

Ahmad, A. ^{[2
,3
]}

Hanifah, S. A. ^{[2
,3
]}

Bella, F. ^{[4
,5
]}

机构：

[1] Univ Benghazi, Fac Arts & Sci, Al Kufrah, Libya

[2] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Chem Sci & Food Technol, Bangi 43600, Selangor, Malaysia

[3] Univ Kebangsaan Malaysia, Polymer Res Ctr, Fac Sci & Technol, Bangi 43600, Selangor, Malaysia

[4] Ist Italiano Tecnol, Ctr Space Human Robot Polito, I-10129 Turin, Italy

[5] Politecn Torino, Dept Appl Sci & Technol DISAT, I-10129 Turin, Italy

来源：

PHYSICA B-CONDENSED MATTER | 2014年 / 450卷

关键词：

UV-curing; Linear polymer; Polymer electrolyte; Lithium salt; Ionic conductivity; Dye sensitized solar cell; CONDUCTIVITY;

D O I：

10.1016/j.physb.2014.05.053

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The effects of LiClO4 and LiFS3SO3 on poly(glycidyl methacrylate)-based solid polymer electrolyte and its photoelectrochemical performance in a dye sensitized solar cell consisting of FTO/TiO2-dye/P(GMA)-LiClO4-EC/Pt were investigated. The electrochemical stability of films was studied by cyclic voltammetry (CV). The highest ionic conductivities obtained were 4.2 x 10(-5) and 3.7 x 10(-6) S cm(-1) for the film containing 30 wt% LiClO4 and 25 wt% LiCF3SO3, respectively. The polymer electrolytes showed electrochemical stability windows up to 3 V and 2.8 V for LiClO4 and LiCF3SO3, respectively. The assembled dye-sensitized solar cell showed a sunlight conversion efficiency of 0.679% (J(sc) = 3 mA cm(-2),V-oc = 0.48 V and FF=0.47), under light intensity of 100 mW cm(-2). (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：151 / 154

页数：4

共 50 条

[31] Effect of polymer electrolyte on the performance of natural dye sensitized solar cells
Adel, R.
Abdallah, T.
Moustafa, Y. M.
Al-sabagh, A. M.
Talaat, H.
SUPERLATTICES AND MICROSTRUCTURES, 2015, 86 : 62 - 67
[32] Influence of electrolyte proportion on the performance of dye-sensitized solar cells
Gu, Peng
Yang, Dingyu
Zhu, Xinghua
Sun, Hui
Wangyang, Peihua
Li, Jitao
Tian, Haibo
AIP ADVANCES, 2017, 7 (10)
[33] Correlation between ionic conductivity and cell performance in solid-state dye-sensitized solar cells employing polymer electrolyte
Cha, Si Young
Lee, Yong-Gun
Kang, Moon-Sung
Kang, Yong Soo
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2010, 211 (2-3) : 193 - 196
[34] Optimization of polymer electrolytes forquasi-solid-state dye-sensitized solar cells
ZHANG Changneng1
2.School of Earth Sciences and Resources
ChineseScienceBulletin, 2004, (19) : 2033 - 2036
[35] Novel in situ crosslinked polymer electrolyte for solid-state dye-sensitized solar cells
Guijie Liang
Zhicheng Zhong
Shaohua Qu
Song Wang
Ke Liu
Jingyang Wang
Jie Xu
Journal of Materials Science, 2013, 48 : 6377 - 6385
[36] Electrochemical Properties of an Agarose-Based Magnetic Polymer Electrolyte in Dye-Sensitized Solar Cells
Guo Xue-Yi
Yi Peng-Fei
Wang Wei-Jia
Yang Ying
ACTA PHYSICO-CHIMICA SINICA, 2012, 28 (03) : 585 - 590
[37] Effect of solvents in liquid electrolyte on the photovoltaic performance of dye-sensitized solar cells
Wu, Jihuai
Lan, Zhang
Lin, Jianming
Huang, Miaoliang
Li, Pinjiang
JOURNAL OF POWER SOURCES, 2007, 173 (01) : 585 - 591
[38] Effects of surfactants on agarose-based magnetic polymer electrolyte for dye-sensitized solar cells
Guo, Xueyi
Yi, Pengfei
Yang, Ying
Cui, Jiarui
Xiao, Si
Wang, Wenyong
ELECTROCHIMICA ACTA, 2013, 90 : 524 - 529
[39] Membrane-based electrolyte sheets for facile fabrication of flexible dye-sensitized solar cells
Chen, Jiake
Lin, Hong
Li, Xin
Zhao, Xiaochong
Hao, Feng
Dong, Siming
ELECTROCHIMICA ACTA, 2011, 56 (17) : 6026 - 6032
[40] Highly efficient quasi-solid state dye-sensitized solar cell with ion conducting polymer electrolyte
Komiya, R
Han, LY
Yamanaka, R
Islam, A
Mitate, T
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 164 (1-3) : 123 - 127

← 1 2 3 4 5 →