A UV-prepared linear polymer electrolyte membrane for dye-sensitized solar cells

被引：62
|
作者：
Imperiyka, M. [1 ]
Ahmad, A. [2 ,3 ]
Hanifah, S. A. [2 ,3 ]
Bella, F. [4 ,5 ]
机构：
[1] Univ Benghazi, Fac Arts & Sci, Al Kufrah, Libya
[2] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Chem Sci & Food Technol, Bangi 43600, Selangor, Malaysia
[3] Univ Kebangsaan Malaysia, Polymer Res Ctr, Fac Sci & Technol, Bangi 43600, Selangor, Malaysia
[4] Ist Italiano Tecnol, Ctr Space Human Robot Polito, I-10129 Turin, Italy
[5] Politecn Torino, Dept Appl Sci & Technol DISAT, I-10129 Turin, Italy
来源：
PHYSICA B-CONDENSED MATTER | 2014年 / 450卷
关键词：
UV-curing; Linear polymer; Polymer electrolyte; Lithium salt; Ionic conductivity; Dye sensitized solar cell; CONDUCTIVITY;
D O I：
10.1016/j.physb.2014.05.053
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
The effects of LiClO4 and LiFS3SO3 on poly(glycidyl methacrylate)-based solid polymer electrolyte and its photoelectrochemical performance in a dye sensitized solar cell consisting of FTO/TiO2-dye/P(GMA)-LiClO4-EC/Pt were investigated. The electrochemical stability of films was studied by cyclic voltammetry (CV). The highest ionic conductivities obtained were 4.2 x 10(-5) and 3.7 x 10(-6) S cm(-1) for the film containing 30 wt% LiClO4 and 25 wt% LiCF3SO3, respectively. The polymer electrolytes showed electrochemical stability windows up to 3 V and 2.8 V for LiClO4 and LiCF3SO3, respectively. The assembled dye-sensitized solar cell showed a sunlight conversion efficiency of 0.679% (J(sc) = 3 mA cm(-2),V-oc = 0.48 V and FF=0.47), under light intensity of 100 mW cm(-2). (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：151 / 154
页数：4
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