Coordination Behaviors and Supramolecular Interactions of 2-(2'-Pyridyl) Imidazoline: Crystal Structure of Its Two Cu(II) Complexes

被引：1

作者：

Wang, Xinmiao ^{[1
]}

Ren, Chunyan ^{[1
]}

Zhang, Wentao ^{[1
]}

Zhou, Xiang ^{[1
]}

Liu, Yang ^{[1
]}

Liu, Ping ^{[1
]}

Wang, Yaoyu ^{[1
]}

机构：

[1] NW Univ Xian, Coll Chem & Mat Sci, Shaanxi Key Lab Physicoinorgan Chem, Key Lab Synthet & Nat Funct Mol Chem,Minist Educ, Xian 710069, Shanxi, Peoples R China

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2014年 / 24卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Imidazoline; Hydrogen bond interactions; Supramolecular; MAGNETIC-PROPERTIES; POLYMERS; 2-IMIDAZOLINES; CONSTRUCTION; NETWORKS; LIGANDS; DESIGN; SERIES; ZN;

D O I：

10.1007/s10904-013-0009-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two new copper coordination complexes, [Cu(PI)(OX)(H2O)]center dot H2O (1) and [Cu(PI)(fum)(H2O)]center dot H2O (2) [PI = 2-(2'-pyridyl) imidazoline, OX2- = dianion of oxalic acid and fum(2-) = dianion of fumaric acid], were synthesized by interface diffusion method based on Cu(II) ions, PI ligands and aliphatic dicarboxylic acids. Complex 1 is a mononuclear complex which spreads into a 3D (4,9)-connected supramolecular network via hydrogen bond interactions, while complex 2 features a 1D zigzag chain with two different orientations. These two compounds are characterized by single crystal X-ray diffraction, powder X-ray diffraction, elemental analyses, infrared spectra, and thermogravimetric analyses.

引用

页码：560 / 567

页数：8

共 46 条

[11] pH-Dependent syntheses of copper-quinoxaline-polyoxotungatate hybrids: variable role of Keggin-type polyanion in different pH conditions [J].

Chi, Ying-Nan ;

Cui, Feng-Yun ;

Jia, Ai-Rui ;

Ma, Xiao-Yu ;

Hu, Chang-Wen .

CRYSTENGCOMM, 2012, 14 (09) :3183-3188

[12] Metal-Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal-Organic Materials [J].

Cook, Timothy R. ;

Zheng, Yao-Rong ;

Stang, Peter J. .

CHEMICAL REVIEWS, 2013, 113 (01) :734-777

[13] Bipyridyl second ligand dependent structural and magnetic properties of Cu(II) complexes with pyridine-2,6-dicarboxylate and water molecule as first ligand [J].

Cui, Shuxin ;

Zhao, Yulong ;

Zhang, Jingping ;

Liu, Qun ;

Zhang, Yan .

CRYSTAL GROWTH & DESIGN, 2008, 8 (10) :3803-3809

[14] Double hydrogen bond- and pi-pi-stacking-assembled two-dimensional copper(I) complex of 2-hydroxyquinoxaline [J].

Dai, J ;

Yamamoto, M ;

KurodaSowa, T ;

Maekawa, M ;

Suenaga, Y ;

Munakata, M .

INORGANIC CHEMISTRY, 1997, 36 (12) :2688-2690

[15] Supramolecular networks in copper(II) malonate complexes [J].

Delgado, Fernando S. ;

Lahoz, Fernando ;

Lloret, Francesc ;

Julve, Miguel ;

Ruiz-Perez, Catalina .

CRYSTAL GROWTH & DESIGN, 2008, 8 (09) :3219-3232

[16] Synthesis, antiproliferative, acute toxicity and assessment of antiandrogenic activities of some newly synthesized steroidal lactams [J].

Dhingra, Neelima ;

Bhardwaj, T. R. ;

Mehta, Neeraj ;

Mukhopadhyay, Tapas ;

Kumar, Ashok ;

Kumar, Manoj .

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2010, 45 (06) :2229-2236

[17] A series of lanthanide-organic polymers incorporating ethyl-4,5-imidazole-dicarboxylato and formate coligand: structures, luminescent and magnetic properties [J].

Feng, Xun ;

Li, Shi-Hui ;

Wang, Li-Ya ;

Zhao, Jian-She ;

Shi, Zhi-Qiang ;

Lei, Peng-Peng .

CRYSTENGCOMM, 2012, 14 (10) :3684-3693

[18]

GHOSH SP, 1983, J INDIAN CHEM SOC, V60, P439

[19] Metal(II) Complexes Based on Benzene-1,2,3-triyldioxy-triacetate: Structures and Photoluminescence Properties [J].

Gong, Yun ;

Jiang, Peng Gang ;

Li, Jian ;

Wu, Tao ;

Lin, Jian Hua .

CRYSTAL GROWTH & DESIGN, 2013, 13 (03) :1059-1066

[20] AN INFRARED STUDY OF THE METAL CHELATES OF SOME IMIDAZOLE DERIVATIVES [J].

HARKINS, TR ;

WALTER, JL ;

HARRIS, OE ;

FREISER, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (02) :260-264

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