Coordination Behaviors and Supramolecular Interactions of 2-(2'-Pyridyl) Imidazoline: Crystal Structure of Its Two Cu(II) Complexes

被引：1

作者：

Wang, Xinmiao ^{[1
]}

Ren, Chunyan ^{[1
]}

Zhang, Wentao ^{[1
]}

Zhou, Xiang ^{[1
]}

Liu, Yang ^{[1
]}

Liu, Ping ^{[1
]}

Wang, Yaoyu ^{[1
]}

机构：

[1] NW Univ Xian, Coll Chem & Mat Sci, Shaanxi Key Lab Physicoinorgan Chem, Key Lab Synthet & Nat Funct Mol Chem,Minist Educ, Xian 710069, Shanxi, Peoples R China

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2014年 / 24卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Imidazoline; Hydrogen bond interactions; Supramolecular; MAGNETIC-PROPERTIES; POLYMERS; 2-IMIDAZOLINES; CONSTRUCTION; NETWORKS; LIGANDS; DESIGN; SERIES; ZN;

D O I：

10.1007/s10904-013-0009-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two new copper coordination complexes, [Cu(PI)(OX)(H2O)]center dot H2O (1) and [Cu(PI)(fum)(H2O)]center dot H2O (2) [PI = 2-(2'-pyridyl) imidazoline, OX2- = dianion of oxalic acid and fum(2-) = dianion of fumaric acid], were synthesized by interface diffusion method based on Cu(II) ions, PI ligands and aliphatic dicarboxylic acids. Complex 1 is a mononuclear complex which spreads into a 3D (4,9)-connected supramolecular network via hydrogen bond interactions, while complex 2 features a 1D zigzag chain with two different orientations. These two compounds are characterized by single crystal X-ray diffraction, powder X-ray diffraction, elemental analyses, infrared spectra, and thermogravimetric analyses.

引用

页码：560 / 567

页数：8

共 46 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[2] SYNTHESIS AND ALPHA-ADRENERGIC ACTIVITIES OF 2-SUBSTITUTED AND 4-SUBSTITUTED IMIDAZOLINE AND IMIDAZOLE ANALOGS [J].

AMEMIYA, Y ;

HONG, SS ;

VENKATARAMAN, BV ;

PATIL, PN ;

SHAMS, G ;

ROMSTEDT, K ;

FELLER, DR ;

HSU, FL ;

MILLER, DD .

JOURNAL OF MEDICINAL CHEMISTRY, 1992, 35 (04) :750-755

[3] Challenges and breakthroughs in recent research on self-assembly [J].

Ariga, Katsuhiko ;

Hill, Jonathan P. ;

Lee, Michael V. ;

Vinu, Ajayan ;

Charvet, Richard ;

Acharya, Somobrata .

SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2008, 9 (01)

[4] Self-Assembled Gelators for Organic Electronics [J].

Babu, Sukumaran Santhosh ;

Prasanthkumar, Seelam ;

Ajayaghosh, Ayyappanpillai .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (08) :1766-1776

[5] Magnetic and temperature-sensitive release gels from supramolecular polymers [J].

Binder, Wolfgang H. ;

Petraru, Laura ;

Roth, Thomas ;

Groh, Peter W. ;

Palfi, Viktoria ;

Keki, Sandor ;

Ivan, Bela .

ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (08) :1317-1326

[6] ASYMMETRIC CATALYSIS .46. ENANTIOSELECTIVE HYDROSILYLATION OF KETONES WITH [RH(COD)CL]2 AND OPTICALLY-ACTIVE NITROGEN LIGANDS [J].

BOTTEGHI, C ;

SCHIONATO, A ;

CHELUCCI, G ;

BRUNNER, H ;

KURZINGER, A ;

OBERMANN, U .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 370 (1-3) :17-31

[7] Probing electronic effects in the asymmetric Heck reaction with the BIPI ligands [J].

Busacca, CA ;

Grossbach, D ;

So, RC ;

O'Brien, EM ;

Spinelli, EM .

ORGANIC LETTERS, 2003, 5 (04) :595-598

[8] Syntheses, crystal structures and magnetic properties of new oxalato-, croconato- and squarato-containing copper(II) complexes [J].

Carranza, J ;

Brennan, C ;

Sletten, J ;

Vangdal, B ;

Rillema, P ;

Lloret, F ;

Julve, M .

NEW JOURNAL OF CHEMISTRY, 2003, 27 (12) :1775-1783

[9] Synthesis and antiproliferative activity of imidazole and imidazoline analogs for melanoma [J].

Chen, Jianjun ;

Wang, Zhao ;

Lu, Yan ;

Dalton, James T. ;

Miller, Duane D. ;

Li, Wei .

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2008, 18 (11) :3183-3187

[10] Two novel hybrid compounds based on [MW12O40]5- (M = B, Al) heteropolyanions and copper coordination polymer with bpp ligands [J].

Chen, Ying ;

Zhou, Baibin ;

Zhao, Jingxiang ;

Li, Yangguang ;

Su, Zhanhua ;

Zhao, Zhifeng .

INORGANICA CHIMICA ACTA, 2010, 363 (14) :3897-3903

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