Large Efficiency Improvement in Cu2ZnSnSe4 Solar Cells by Introducing a Superficial Ge Nanolayer

被引:164
作者
Giraldo, Sergio [1 ]
Neuschitzer, Markus [1 ]
Thersleff, Thomas [2 ]
Lopez-Marino, Simon [1 ]
Sanchez, Yudania [1 ]
Xie, Haibing [1 ]
Colina, Monica [1 ]
Placidi, Marcel [1 ]
Pistor, Paul [1 ]
Izquierdo-Roca, Victor [1 ]
Leifer, Klaus [2 ]
Perez-Rodriguez, Alejandro [1 ,3 ]
Saucedo, Edgardo [1 ]
机构
[1] Catalonia Inst Energy Res IREC, Barcelona 08930, Spain
[2] Uppsala Univ, Dept Engn Sci, Angstrom Lab, S-75121 Uppsala, Sweden
[3] Univ Barcelona, IN2UB, E-08028 Barcelona, Spain
关键词
THIN-FILMS; TEMPERATURE;
D O I
10.1002/aenm.201501070
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A large improvement in Cu2ZnSnSe4 solar cell efficiency is presented based on the introduction of a Ge superficial nanolayer. This improvement is explained by three complementary effects: the formation of a liquid Ge-related phase, the possible reduction of Sn multicharge states, and the formation of GeOx nanoinclusions, which lead to an impressive solar cell (VOC) increase. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页数:6
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