End group modification of poly(acrylates) obtained via ATRP: a user guide

被引：64
作者：
Anastasaki, Athina [1 ]
Willenbacher, Johannes [1 ]
Fleischmann, Carolin [1 ]
Gutekunst, Will R. [1 ,2 ]
Hawker, Craig J. [1 ]
机构：
[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
[2] Georgia Inst Technol, ESI, Atlanta, GA 30332 USA
来源：
POLYMER CHEMISTRY | 2017年 / 8卷 / 04期
基金：
美国国家科学基金会;
关键词：
LIVING RADICAL POLYMERIZATION; SILYL ENOL ETHERS; SET-LRP; CLICK CHEMISTRY; METHYL-METHACRYLATE; CHAIN TRANSFER; RAFT PROCESS; POLYMERS; COPOLYMERS; PRECISION;
D O I：
10.1039/c6py01993e
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The versatile and high yielding functionalization of polymer end groups is a critical tool for controlling material properties and/or for successful post polymerization reactions. In this report, bromine-terminated poly(methyl acrylate) derivatives are used as a model system for identifying conditions leading to quantitative transformation of the end group. A wide range of small molecules and associated reactions for the introduction of specific acidic, basic, hydrophilic or hydrophobic functionality are described. Analysis by SEC, H-1 NMR and MALDI-ToF-MS provides evidence for full conversion of the end group. The user-friendly nature of these procedures serve as a powerful strategy for the synthesis of end functionalized polymers.
引用
收藏
页码：689 / 697
页数：9
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