Temperature dependence of antiferromagnetic susceptibility in ferritin

被引:53
作者
Silva, N. J. O. [1 ]
Millan, A.
Palacio, F.
Kampert, E.
Zeitler, U.
Rakoto, H.
Amaral, V. S.
机构
[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain
关键词
antiferromagnetic materials; biomagnetism; magnetic particles; magnetic susceptibility; magnetisation; molecular biophysics; nanoparticles; proteins; DES GRAINS FINS; MAGNETIZATION; NANOPARTICLES; FERRIHYDRITE;
D O I
10.1103/PhysRevB.79.104405
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We show that antiferromagnetic susceptibility in ferritin increases with temperature between 4.2 and 180 K (i.e., below the Neel temperature) when taken as the derivative of the magnetization at high fields (30x10(4) Oe). This behavior contrasts with the decrease in temperature previously found, where the susceptibility was determined at lower fields (5x10(4) Oe). At high fields (up to 50x10(4) Oe) the temperature dependence of the antiferromagnetic susceptibility in ferritin nanoparticles approaches the normal behavior of bulk antiferromagnets and nanoparticles considering superantiferromagnetism, this latter leading to a better agreement at high field and low temperature. The contrast with the previous results is due to the insufficient field range used (< 5x10(4) Oe), not enough to saturate the ferritin uncompensated moment.
引用
收藏
页数:7
相关论文
共 28 条
[1]   Anomalous properties of magnetic nanoparticles [J].
Berkowitz, AE ;
Kodama, RH ;
Makhlouf, SA ;
Parker, FT ;
Spada, FE ;
McNiff, EJ ;
Foner, S .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 196 :591-594
[2]   Relaxometry and magnetometry of ferritin [J].
Brooks, RA ;
Vymazal, J ;
Goldfarb, RB ;
Bulte, JWM ;
Aisen, P .
MAGNETIC RESONANCE IN MEDICINE, 1998, 40 (02) :227-235
[3]   Intrinsic volume scaling of thermoinduced magnetization in antiferromagnetic nanoparticles [J].
Brown, G ;
Janotti, A ;
Eisenbach, M ;
Stocks, GM .
PHYSICAL REVIEW B, 2005, 72 (14)
[4]   Non-Langevin behaviour of the uncompensated magnetization in nanoparticles of artificial ferritin [J].
Gilles, C ;
Bonville, P ;
Wong, KKW ;
Mann, S .
EUROPEAN PHYSICAL JOURNAL B, 2000, 17 (03) :417-427
[5]   Magnetic hysteresis and superantiferromagnetism in ferritin nanoparticles [J].
Gilles, C ;
Bonville, P ;
Rakoto, H ;
Broto, JM ;
Wong, KKW ;
Mann, S .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2002, 241 (2-3) :430-440
[6]   Very high field magnetization and AC susceptibility of native horse spleen ferritin [J].
Guertin, R. P. ;
Harrison, N. ;
Zhou, Z. X. ;
McCall, S. ;
Drymiotis, F. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2007, 308 (01) :97-100
[7]   Occurrence and constitution of natural and synthetic ferrihydrite, a widespread iron oxyhydroxide [J].
Jambor, JL ;
Dutrizac, JE .
CHEMICAL REVIEWS, 1998, 98 (07) :2549-2585
[8]   The structure of six-line ferrihydrite [J].
Jansen, E ;
Kyek, A ;
Schäfer, W ;
Schwertmann, U .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2002, 74 (Suppl 1) :S1004-S1006
[9]   Effects of spin non-collinearities in magnetic nanoparticles [J].
Kachkachi, H. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2007, 316 (02) :248-254
[10]   FERRITIN - A MODEL SUPERPARAMAGNET [J].
KILCOYNE, SH ;
CYWINSKI, R .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1995, 140 :1466-1467