A new homogeneous zinc complex with increased reactivity for the intramolecular hydroamination of alkenes

被引:88
作者
Dochnahl, Maximilian
Pissarek, Jens-Wolfgang
Blechert, Siegfried
Loehnwitz, Karolin
Roesky, Peter W.
机构
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
[2] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany
关键词
D O I
10.1039/b607597e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new zinc compound N-cyclohexyl-2-(cyclohexylamino) troponiminate zinc methyl, [(Cy)(2)ATI] ZnMe (2), was synthesized and showed a superior reactivity in the intramolecular hydroamination reaction of non-activated alkenes compared to previously reported homogeneous zinc complexes.
引用
收藏
页码:3405 / 3407
页数:3
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