Multicomponent metal-organic framework derivatives for optimizing the selective catalytic performance of styrene epoxidation reaction

被引:48
作者
Hui, Junfeng [1 ]
Chu, Huimin [1 ]
Zhang, Wenlei [2 ]
Shen, Yu [3 ,4 ]
Chen, Wanzheng [3 ,4 ]
Hu, Yu [3 ,4 ]
Liu, Wan [1 ]
Gao, Cong [3 ,4 ]
Guo, Shaohua [3 ,4 ]
Xiao, Gengwu [3 ,4 ]
Li, Sheng [3 ,4 ]
Fu, Yu [2 ]
Fan, Daidi [1 ]
Zhang, Weina [3 ,4 ]
Huo, Fengwei [3 ,4 ]
机构
[1] Northwest Univ, Sch Chem Engn, Shaanxi R&D Ctr Biomat & Fermentat Engn, Shaanxi Key Lab Degradable Biomed Mat, Xian 710069, Shaanxi, Peoples R China
[2] Northeastern Univ, Coll Sci, Shenyang 100819, Liaoning, Peoples R China
[3] Nanjing Tech Univ NanjingTech, Key Lab Flexible Elect KLOFE, 30 South Puzhu Rd, Nanjing 211800, Jiangsu, Peoples R China
[4] Nanjing Tech Univ NanjingTech, Inst Adv Mat IAM, 30 South Puzhu Rd, Nanjing 211800, Jiangsu, Peoples R China
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
CHEMICAL HYDROGEN STORAGE; OXYGEN REDUCTION REACTION; DOPED POROUS CARBON; CO-BASED CATALYSTS; HIGH-SURFACE-AREA; AEROBIC EPOXIDATION; AMMONIA BORANE; NANOPARTICLES; OXIDATION; EFFICIENT;
D O I
10.1039/c8nr01336e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Multicomponent metal-organic framework (MOF) derivatives have attracted strong interest in energy and environmental fields. However, most of the papers focus on single MOF derivatives; reports on multicomponent MOF derivatives and their catalytic studies are relatively few. Here, we report an easy-to-operate strategy to obtain multicomponent MOF derivatives by treating multicomponent MOFs under a suitable gas atmosphere and at high temperature. We used ZIF-67 as a template to introduce Zn and successfully obtained multicomponent MOFs. After carbonization, the multicomponent MOF derivatives with Co and CoO nanoparticles exhibit higher conversion of styrene (approximate to 99%), higher selectivity (approximate to 70%) and better stability compared to MOFs and single component MOF derivatives.
引用
收藏
页码:8772 / 8778
页数:7
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