Ionic liquids from the cationic cobalt(III) Schiff base complex, [Co(acacen)L2][Tf2N] (acacen = N,N′-bis(acetylacetone)ethylenediamine, Tf2N = bis(trifluoromethanesulfonyl)amide)

被引：4

作者：

Okuhata, Megumi ^{[1
]}

Mochida, Tomoyuki ^{[1
]}

机构：

[1] Kobe Univ, Dept Chem, Grad Sch Sci, Kobe, Hyogo 657, Japan

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 67卷 / 08期

关键词：

Ionic liquid; Thermal properties; Acacen; Schiff base; Axial ligand; CRYSTALS; SALTS;

D O I：

10.1080/00958972.2014.917295

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ionic liquids comprising cationic cobalt(III) complexes [Co(acacen)L-2][Tf2N] (L = 3-butylpyridine (1), 1-butylimidazole (2); acacen = N,N'-bis(acetylacetone)ethylenediamine, Tf2N = bis(trifluoromethanesulfonyl) amide) were prepared. 1 is a liquid at room temperature and exhibits a glass transition at -12 degrees C, whereas 2 is a solid at room temperature with a melting point of 74.6 degrees C and glass transition temperature of -15 degrees C upon cooling from the melt. These salts are reddish brown diamagnetic materials that are stable against air and water; these properties differ from those of the corresponding iron(III) salt. Desorption of the axial ligands of 1 and 2 occurs at 180 and 207 degrees C, respectively.

引用

页码：1361 / 1366

页数：6

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