Synthesis, Characterization, and X-Ray Crystal Structure of a New 2D Cu(II) Complex with a Novel 4,4' -Diazenediyldiphthalic Acid

被引：0

作者：

Wang, Fumin ^{[1
]}

机构：

[1] Weinan Teachers Univ, Dept Chem & Chem Engn, Weinan 714000, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2009年 / 39卷 / 02期

关键词：

Cu complex; crystal structure; porous framework; topology; COORDINATION POLYMERS; IONS;

D O I：

10.1080/15533170902772966

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An exploration of the cadmium-L system under hydrothermal condition has led to the isolation of a novel framework [Cu2(L)(H2O)2] 2H2O n (H4L = 4,4' -diazenediyldiphthalic acid). Single-crystal X-ray analyses reveal that it crystallizes in the monoclinic space group P21/c. a = 17.182(7) ,b = 6.677(3) ,c = 8.095(4) , = 90.247(7). The CuII ions are linked into an extended 2-D rectangle-like structure via L ligands, which represents an attractive four-connected gear topological network.

引用

页码：116 / 119

页数：4

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