SYNTHESIS AND CHARACTERIZATION OF MALEIC ANHYDRIDE COPOLYMERS AND THEIR DERIVATIVES. 4. SYNTHESIS AND CHARACTERIZATION OF MALEIC ANHYDRIDE-ACRYLONITRILE COPOLYMERS

被引:0
作者
Chitanu, Gabrielle Charlotte [1 ]
Popescu, Irina [1 ]
Pelin, Irina Mihaela [1 ]
Avadanei, Mihaela Luliana [1 ]
机构
[1] Roumanian Acad, Petru Poni Inst Macromol Chem, Iasi 700487, Romania
关键词
maleic anhydride-acrylonitrile copolymers; radical copolymerization; copolymer composition;
D O I
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The copolymers of maleic acid with acrylonitrile can be applied in the fabrication of membranes for ultrafiltration, pervaporation and enzyme-immobilization. In this paper we present new results on the synthesis of maleic anhydride-acrylonitrile copolymer by radical copolymerization in organic solvents. We have examined the effect of the synthesis conditions: solvent, monomer ratio, and monomer concentration on the composition and molar mass of the copolymer. The composition of copolymers was determined by different methods: elemental analysis, conductometric titration in water/organic media, titration in nonaqueous medium, FTIR and H-1 NMR spectra. The data were compared and the most reliable and convenient method was identified.
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页码:577 / +
页数:8
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