Electrostatic attraction between ionic reverse micelles with dielectric discontinuity

被引：2
|
作者：
Chen, PL [1 ]
机构：
[1] Natl Cent Univ, Dept Phys, Chungli 320, Taiwan
[2] Natl Cent Univ, Ctr Complex Syst, Chungli 320, Taiwan
来源：
JOURNAL OF CHEMICAL PHYSICS | 2002年 / 117卷 / 20期
关键词：
D O I：
10.1063/1.1516596
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We have calculated the thermally-averaged electrostatic attractive potential between two spherical ionic reverse micelles in a medium of a different dielectric constant. Specifically the attractions between the charge density fluctuations in one micelle and interface polarizations on the other are computed. For water-in-oil microemulsions, we find that these contributions completely overwhelm those from correlated fluctuations in charge densities between two micelles. (C) 2002 American Institute of Physics.
引用
收藏
页码：9460 / 9464
页数：5
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