Enhanced Optical Performance of BaMgAl10O17:Eu2+ Phosphor by a Novel Method of Carbon Coating

被引:58
作者
Yin, Liang-Jun [1 ,5 ]
Dong, Juntao [1 ]
Wang, Yinping [1 ]
Zhang, Bi [2 ]
Zhou, Zheng-Yang [3 ]
Jian, Xian [1 ]
Wu, Mengqiang [1 ]
Xu, Xin [2 ]
van Ommen, J. Ruud [4 ]
Hintzen, Hubertus T. [5 ]
机构
[1] Univ Elect Sci & Technol China, Sch Energy Sci & Engn, 2006 Xiyuan Rd, Chengdu 611731, Peoples R China
[2] Univ Sci & Technol China, Dept Mat Sci & Engn, Lab Mat Energy Convers, Hefei 230026, Peoples R China
[3] Peking Univ, Coll Chem & Mol Engn, 5 Yiheyuan Rd, Beijing 100871, Peoples R China
[4] Delft Univ Technol, Fac Sci Appl, Dept Chem Engn, Julianalaan 136, NL-2628 BL Delft, Netherlands
[5] Delft Univ Technol, Fac Sci Appl, Luminescent Mat Res Grp, Mekelweg 15, NL-2629 JB Delft, Netherlands
基金
中国国家自然科学基金;
关键词
THERMAL-STABILITY; DEGRADATION; PHOTOLUMINESCENCE;
D O I
10.1021/acs.jpcc.5b10215
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Many strategies have been adopted to improve thermal degradation of phosphors. Because of the stability and high transmittance of graphene, here we report a novel method of carbon coating on BaMgAl10O17:Eu2+ (BAM) phosphor particles through chemical vapor deposition. The chemical composition, microstructure, and luminescence performance of carbon-coated BAM were characterized carefully. This coating can be controlled within 3-10 atomic layers, depending on the reaction time. Because of the decrease of surface defects and the effective weakening effect of oxidizing Eu2+ to Eu3+ after carbon coating, different layer numbers showed an obvious effect on the optical properties of carbon-coated BAM. Carbon-coated BAM phosphors had higher emission intensity and better oxidation resistance at high temperature than uncoated BAM phosphors. These results indicate that the method of carbon coating on phosphor particles is a promising way to improve the luminescence properties of other phosphors used in lighting and display devices.
引用
收藏
页码:2355 / 2361
页数:7
相关论文
共 29 条
[1]   On BaMgAl10O17 :: Eu2+ phosphor degradation mechanism:: thermal treatment effects [J].
Bizarri, G ;
Moine, B .
JOURNAL OF LUMINESCENCE, 2005, 113 (3-4) :199-213
[2]   Making graphene visible [J].
Blake, P. ;
Hill, E. W. ;
Castro Neto, A. H. ;
Novoselov, K. S. ;
Jiang, D. ;
Yang, R. ;
Booth, T. J. ;
Geim, A. K. .
APPLIED PHYSICS LETTERS, 2007, 91 (06)
[3]   Optical constants of graphene layers in the visible range [J].
Bruna, M. ;
Borini, S. .
APPLIED PHYSICS LETTERS, 2009, 94 (03)
[4]  
Chao L., 2006, J RARE EARTH, V24, P153, DOI [10.1016/S1002-0721(07)60347-0, DOI 10.1016/S1002-0721(07)60347-0]
[5]   Microstructure and luminescence of surface-coated nano-BaMgAl10O17:Eu2+ blue phosphor [J].
Chen, Z. ;
Yan, Y. W. ;
Liu, J-M. ;
Yin, Yi ;
Wen, Hongmin ;
Liao, Gaohua ;
Wu, Chunlan ;
Zao, Liangqian ;
Liu, Dehui ;
Tian, Hongmin ;
Zhang, Chenshu ;
Li, Shuidi .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 478 (1-2) :679-683
[6]   PROBABILITIES FOR RADIATIVE AND NONRADIATIVE DECAY OF PR3+ ION IN LAALO3 [J].
DELSART, C ;
PELLETIE.N .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1973, 6 (07) :1277-1291
[7]   Synthesis and properties of Eu2+ activated blue phosphors [J].
Ekambaram, S ;
Patil, KC .
JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 248 (1-2) :7-12
[8]   Optical detection and characterization of graphene by broadband spectrophotornetry [J].
Gray, Alexander ;
Balooch, Mehdi ;
Allegret, Stephane ;
De Gendt, Stefan ;
Wang, Wei-E .
JOURNAL OF APPLIED PHYSICS, 2008, 104 (05)
[9]   Characterization of host-lattice emission and energy transfer in BaMgAl10O17:Eu2+ [J].
Howe, B ;
Diaz, AL .
JOURNAL OF LUMINESCENCE, 2004, 109 (01) :51-59
[10]   Improved thermal resistance of spherical BaMgAl10O17:Eu blue phosphor prepared by spray pyrolysis [J].
Jung, KY ;
Lee, DY ;
Kang, YC .
JOURNAL OF LUMINESCENCE, 2005, 115 (3-4) :91-96