Pressure-induced phase transitions in crystalline L-serine studied by single-crystal and high-resolution powder X-ray diffraction

被引：79
作者：
Boldyreva, E. V.
Sowa, H.
Seryotkin, Yu. V.
Drebushchak, T. N.
Ahsbahs, H.
Chernyshev, V.
Dmitriev, V.
机构：
[1] Novosibirsk State Univ, Novosibirsk 630090, Russia
[2] RAS, Inst Solid State Chem & Mechanochem SB, Novosibirsk 630128, Russia
[3] Univ Marburg, D-35032 Marburg, Germany
[4] RAS, Inst Geol & Mineral SB, Novosibirsk 630090, Russia
[5] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
[6] Swiss Norwegian Beamlines, ESRF, F-38043 Grenoble, France
来源：
CHEMICAL PHYSICS LETTERS | 2006年 / 429卷 / 4-6期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1016/j.cplett.2006.08.092
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Pressure induces two isosymmetric reversible polymorphic transitions in L-serine related to a junipwise change in the hydrogen bond networks and the conformation of the zwitter-ions. Single-crystal X-ray diffraction in situ allowed to find the structure of L-serine III at 8.0 GPa (the phase was previously reported based on Raman spectra [Kolesnik et al., Doklady Chem. 404 (2005) 169]). High-resolution X-ray powder diffraction data with a synchrotron radiation source suggest the formation of a superstructure with a and c parameters tripled as compared with the single-crystal model. (c) 2006 Elsevier B.V. All rights reserved.
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收藏
页码：474 / 478
页数：5
相关论文
共 20 条
[11]  
FINGER LW, 1978, AM MINERAL, V63, P337
[12]  
FUJISHIRO I, 1981, P 8 AIRAPT C, P608
[13]   Raman observation of a new (ζ) polymorph of glycine? [J].
Goryainov, SV ;
Boldyreva, E ;
Kolesnik, EN .
CHEMICAL PHYSICS LETTERS, 2006, 419 (4-6) :496-500
[14]   DIFFRACTED BEAM CRYSTAL CENTERING AND ITS APPLICATION TO HIGH-PRESSURE CRYSTALLOGRAPHY [J].
KING, HE ;
FINGER, LW .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1979, 12 (AUG) :374-378
[15]   Different behavior of L- and DL-serine crystals at high pressures:: Phase transitions in L-serine and stability of the DL-serine structure [J].
Kolesnik, EN ;
Goryainov, SV ;
Boldyreva, EV .
DOKLADY PHYSICAL CHEMISTRY, 2005, 404 (1-3) :169-172
[16]   High-pressure polymorphism in L-cysteine: the crystal structures of L-cysteine-III and L-cysteine-IV [J].
Moggach, SA ;
Allan, DR ;
Clark, SJ ;
Gutmann, MJ ;
Parsons, S ;
Pulham, CR ;
Sawyer, L .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2006, 62 (296-309) :296-309
[17]   Effect of pressure on the crystal structure of L-serine-I and the crystal structure of L-serine-II at 5.4 GPa [J].
Moggach, SA ;
Allan, DR ;
Morrison, CA ;
Parsons, S ;
Sawyer, L .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2005, 61 (01) :58-68
[18]   CALIBRATION OF PRESSURE-DEPENDENCE OF R1 RUBY FLUORESCENCE LINE TO 195 KBAR [J].
PIERMARINI, GJ ;
BLOCK, S ;
BARNETT, JD ;
FORMAN, RA .
JOURNAL OF APPLIED PHYSICS, 1975, 46 (06) :2774-2780
[19]  
SHELDRICK G, 1997, SHELXL PROGRAM REFIN
[20]  
Tsybulya SV, 2004, DIFFRACTION ANALYSIS OF THE MICROSTRUCTURE OF MATERIALS, P93
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