Water-Borne Polymer/Graphene Nanocomposites

被引：25
作者：
Arzac, Alejandro [1 ,2 ]
Patricia Leal, Gracia [1 ,2 ]
Carlos de la Cal, Jose [1 ,2 ]
Tomovska, Radmila [1 ,2 ,3 ]
机构：
[1] Univ Basque Country UPV EHU, Fac Ciencias Quim, Jose Mari Korta Zentroa, Polymat, Tolosa Hiribidea 72, Donostia San Sebastian 20018, Spain
[2] Univ Basque Country UPV EHU, Fac Ciencias Quim, Jose Mari Korta Zentroa, Dept Quim Aplicada, Tolosa Hiribidea 72, Donostia San Sebastian 20018, Spain
[3] Ikerbasque, Basque Fdn Sci, E-48011 Bilbao, Spain
来源：
MACROMOLECULAR MATERIALS AND ENGINEERING | 2017年 / 302卷 / 01期
关键词：
emulsion; graphene; graphene/polymer composites; water-borne composites; PICKERING EMULSION POLYMERIZATION; GRAPHENE OXIDE/POLYMER COMPOSITES; IN-SITU POLYMERIZATION; MINIEMULSION POLYMERIZATION; FUNCTIONALIZED GRAPHENE; GRAPHITE OXIDE; ELECTRICAL-CONDUCTIVITY; CARBON NANOTUBES; POLYSTYRENE NANOCOMPOSITES; AQUEOUS DISPERSIONS;
D O I：
10.1002/mame.201600315
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The potential of polymerization in a dispersed system as an attractive technique for polymer/graphene composite synthesis is discussed. This overview is focused on the preparation of graphene/polymer composite materials by two methods: (i) emulsion mixing or blending of polymer and graphene aqueous dispersions, and (ii) in situ polymerization in a dispersed system (emulsion, miniemulsion, microemulsion, and Pickering-stabilized emulsion). Various methods for the stabilization of graphene nanoplatelets (GNPs) prior to composite preparation are presented, and the established specific interactions between the filler and the matrix are discussed. The determination of the electrical conductivity and the opportunity offered by polymerization in a dispersed system for the formation of a segregated network of graphene filler in the frame of a polymer matrix are presented. The mechanical and thermal properties of the composites are also discussed. A short summary of the open questions regarding the synthesis of water-borne polymer/graphene composites is presented.
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页数：30
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