One-pot conversion of tetraiminodiphenols to diiminodiaminodiphenols via methyl transfer at aluminium

被引：16

作者：

Arbaoui, Abdessamad ^{[1
]}

Redshaw, Carl ^{[1
]}

Hughes, David L. ^{[1
]}

机构：

[1] Univ E Anglia, Sch Chem Sci & Pharm, Norwich NR4 7TJ, Norfolk, England

来源：

SUPRAMOLECULAR CHEMISTRY | 2009年 / 21卷 / 1-2期

关键词：

Schiff base; macrocycle; trimethylaluminium; imine; amine; SCHIFF-BASE MACROCYCLES; ETHYLENE POLYMERIZATION; METAL-COMPLEXES; STRUCTURAL-CHARACTERIZATION; ANTIMICROBIAL ACTIVITY; BINUCLEATING LIGANDS; CRYSTAL-STRUCTURE; OXYGEN INSERTION; COORDINATION; CONFORMATION;

D O I：

10.1080/10610270802438846

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The [2+2] macrocyclic Schiff base {[2-(OH)-5-(tBu)C6H2-1,3-CH][(CH2CH2)(2-C6H4N)2]}2 (1) is readily converted to the diiminodiamine {[2-(OH)-5-(tBu)C6H2-1-(CH)-3-C(Me)H][(CH2CH2)(2-(N)-2'-C6H4NH)2]}2 (2) via methyl group transfer from Me3Al (four equivalents) and subsequent hydrolysis. When compound 1 is reacted with two equivalents of Me3Al, the dinuclear complex {(Me2Al)[2-(O)-5-(tBu)C6H2-1,3-(CH)2][(CH2CH2)(2-C6H4)2N)2]}2 (3) is formed. The structures of the macrocycles 1 and 2 are described (in the case of 1, the toluene solvate has also been structurally characterised). [image omitted].

引用

页码：35 / 43

页数：9

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