Foaming Behaviors and Mechanical Properties of Injection-Molded Polylactide/Cotton-Fiber Composites

被引:18
作者
Zhang, Xiaoli [1 ,3 ]
Ding, Weidan [1 ]
Chang, Eunse [1 ]
Chen, Xuefeng [2 ]
Chen, Jingbo [3 ]
Park, Chul B. [1 ]
Shen, Changyu [3 ]
机构
[1] Univ Toronto, Microcellular Plast Mfg Lab, Dept Mech & Ind Engn, Toronto, ON M5S 3G8, Canada
[2] China Natl Pulp & Paper Res Inst, Beijing 100102, Peoples R China
[3] Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 450001, Peoples R China
基金
中国国家自然科学基金;
关键词
CRYSTALLIZATION BEHAVIOR; VISUAL OBSERVATION; MORPHOLOGY; PLA; CO2; ADDITIVES;
D O I
10.1021/acs.iecr.0c03348
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this study, we investigated the effects of short shot size, lubricant, and cotton fibers on the foaming and mechanical properties of poly(lactic acid) (PLA). The short shot filling capacity influenced the expansion ratio and void fraction of PLA and PLA/cotton-fiber dramatically, a set shot size of 45 cm(3) (80%) filled part presented a relatively uniform cell morphology and the improved impact strength, while 38 cm(3) (70%) filled ones exhibited an inferior cell structure, low tensile strength, and impact strength. Because of the microsize and the difficult dispersion of the cotton fiber, the tensile properties of all fiber filled solid and foamed samples decreased. Compared to the solid injection molded neat PLA, an impact strength of 52 cm(3) (100%) fully filled and 45 cm(3) filled foaming neat PLA climbed from 32.48 to 42.36 and 47.40 J/m, respectively. Moreover, at the 45 cm(3) filled level, the impact strength of 10 wt % cotton fiber added composite is 31.24 J/m, a 3.8% slight decrease was calculated compared with the solid neat PLA. The composite with a higher fiber filling content of 20 wt % resulted in a severe cell deformation and obvious less cell asymmetry, and a less impact strength of 28.65 J/m was obtained. The filling of the cotton fiber could slightly change the crystallization behavior of PLA through the injection foaming process, and the increasing of crystallinity was limited.
引用
收藏
页码:17885 / 17893
页数:9
相关论文
共 42 条
[11]   Non-isothermal crystallization behaviors of poly(lactic acid)/cellulose nanofiber composites in the presence of CO2 [J].
Ding, WeiDan ;
Chu, Raymond K. M. ;
Mark, Lun Howe ;
Park, Chul B. ;
Sain, Mohini .
EUROPEAN POLYMER JOURNAL, 2015, 71 :231-247
[12]   Poly(lactic acid) fiber: An overview [J].
Gupta, Bhuvanesh ;
Revagade, Nilesh ;
Hilborn, Jons .
PROGRESS IN POLYMER SCIENCE, 2007, 32 (04) :455-482
[13]   The Mechanical/Thermal Properties of Microcellular Injection-Molded Poly-Lactic-Acid Nanocomposites [J].
Hwang, Shyh-Shin ;
Hsu, Peming P. ;
Yeh, Jui-Ming ;
Chang, Kung-Chin ;
Lai, Ying-Zhong .
POLYMER COMPOSITES, 2009, 30 (11) :1625-1630
[14]   Visual Observation and Numerical Studies of N2 vs. CO2 Foaming Behavior in Core-Back Foam Injection Molding [J].
Ishikawa, Takeshi ;
Taki, Kentaro ;
Ohshima, Masahiro .
POLYMER ENGINEERING AND SCIENCE, 2012, 52 (04) :875-883
[15]   Visual Observation and Numerical Studies of Polymer Foaming Behavior of Polypropylene/Carbon Dioxide System in a Core-back Injection Molding Process [J].
Ishikawa, Takeshi ;
Ohshima, Masahiro .
POLYMER ENGINEERING AND SCIENCE, 2011, 51 (08) :1617-1625
[16]   Extruded PLA/clay nanocomposite foams blown with supercritical CO2 [J].
Keshtkar, M. ;
Nofar, M. ;
Park, C. B. ;
Carreau, P. J. .
POLYMER, 2014, 55 (16) :4077-4090
[17]   Reducing material costs with microcellular/fine-celled foaming [J].
Lee, John W. S. ;
Park, Chul B. ;
Kim, Seong G. .
JOURNAL OF CELLULAR PLASTICS, 2007, 43 (4-5) :297-312
[18]   Use of nitrogen as a blowing agent for the production of fine-celled high-density polyethylene foams [J].
Lee, John W. S. ;
Park, Chul B. .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2006, 291 (10) :1233-1244
[19]   Foaming of Poly(lactic acid) Based on Its Nonisothermal Crystallization Behavior under Compressed Carbon Dioxide [J].
Li, Da-chao ;
Liu, Tao ;
Zhao, Ling ;
Lian, Xiao-song ;
Yuan, Wei-kang .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (04) :1997-2007
[20]   Influence and prediction of processing parameters on the properties of microcellular injection molded thermoplastic polyurethane based on an orthogonal array test [J].
Mi, Hao-Yang ;
Jing, Xin ;
Peng, Jun ;
Turng, Lih-Sheng ;
Peng, Xiang-Fang .
JOURNAL OF CELLULAR PLASTICS, 2013, 49 (05) :439-458