Direct allylation of alcohols using allyltrimethylsilane: a move towards an economical and ecological protocol for C-C bond formation

被引：14

作者：

Chaskar, Atul ^{[1
]}

Murugan, Kaliyappan ^{[2
]}

机构：

[1] Inst Chem Technol, Bombay 400019, Maharashtra, India

[2] Natl Taiwan Univ, Taipei 10764, Taiwan

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2014年 / 4卷 / 07期

关键词：

ONE-POT SYNTHESIS; NUCLEOPHILIC-SUBSTITUTION-REACTIONS; BRONSTED ACID CATALYST; HOSOMI-SAKURAI REACTIONS; DIRECT COUPLING REACTION; KINESIN SPINDLE PROTEIN; VIVO ANTITUMOR-ACTIVITY; PROPARGYLIC ALCOHOLS; HOMOALLYL ETHERS; LEWIS-ACID;

D O I：

10.1039/c4cy00043a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The allylation of benzylic, allylic and propargylic alcohols by means of allyltrimethylsilane represents one of the most powerful, elegant and practical methods for the formation of carbon-carbon bonds in organic synthesis. This method has received considerable attention owing to the ability of allylated compounds to undergo further synthetic manipulations. The aim of this review is to summarise the recent trends and developments reported in the literature and to assist in the creation of novel methodologies.

引用

页码：1852 / 1868

页数：17

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