Selective catalytic reduction of NO with NH3 over Mo-Fe/beta catalysts: the effect of Mo loading amounts

被引：32

作者：

Deng, Jianlin ^{[1
]}

Liu, Jixing ^{[1
]}

Song, Weiyu ^{[1
]}

Zhao, Zhen ^{[1
]}

Zhao, Liang ^{[1
]}

Zheng, Huiling ^{[1
]}

Lee, Alex Chinghuan ^{[2
]}

Chen, Yongsheng ^{[2
]}

Liu, Jian ^{[1
]}

机构：

[1] China Univ Petr, Beijing Key Lab Oil & Gas Pollut Control, State Key Lab Heavy Oil Proc, 18 Fuxue Rd, Beijing 102249, Peoples R China

[2] Chinese Univ Hong Kong, Dept Mech & Automat Engn, Hong Kong, Hong Kong, Peoples R China

来源：

RSC ADVANCES | 2017年 / 7卷 / 12期

基金：

中国国家自然科学基金;

关键词：

DENSITY-FUNCTIONAL THEORY; MIXED-OXIDE CATALYST; FE-BEA; LOW-TEMPERATURE; N2O DECOMPOSITION; SCR-NOX; AMMONIA; SPECTROSCOPY; ZEOLITES; FE-ZSM-5;

D O I：

10.1039/c6ra27126j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of Mox-Fe/beta catalysts with constant Fe and variable Mo content were synthesized and investigated for selective catalytic reduction (SCR) of NOx with NH3. It was found that the Mo-0.2-Fe/beta catalyst exhibited excellent activity, N-2 selectivity and preferable resistance to H2O and SO2. The Mo-x-Fe/ beta catalysts were characterized by various analytical techniques. TEM and SEM images showed that the addition of Mo could enhance the dispersion of iron oxides. The results of NH3-TPD and Py-IR indicated that the introduction of Mo resulted in a change of Bronsted acidity, which was associated with high-temperature SCR activity. XPS and XANES results showed that the introduction of Mo resulted in a change of Fe2+ content, which determined the low-temperature activity. DFT calculations showed the strong effects of Mo on the crystal structure, charge distribution and oxygen vacancy formation energy of iron oxides, which further explained the role of Mo in the catalyst behaviors during the SCR process.

引用

页码：7130 / 7139

页数：10

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