A twofold interpenetrated 3-D Cu(II) coordination polymer based on 5-(pyridin-4-yl)isophthalic acid: synthesis, crystal structure, and magnetic properties

被引：1
作者：
Zhang, Qing-Fu [1 ]
Zhang, Jing-Jing [1 ]
Lei, Ming-Yuan [1 ]
机构：
[1] Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2016年 / 69卷 / 02期
关键词：
Cu(II) coordination polymer; 5-(pyridin-4-yl)isophthalic acid ligand; crystal structure; magnetic properties; METAL-ORGANIC FRAMEWORKS; SECONDARY BUILDING UNITS; PYRIDYL-BIS-AMIDE; LUMINESCENT PROPERTIES; SORPTION PROPERTY; 2D LAYER; CO-II; NI-II; LIGANDS; COMPLEXES;
D O I：
10.1080/00958972.2015.1110239
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new copper(II) coordination polymer, [Cu(PIA)2H(2)O](n) (1) [H(2)PIA=5-(pyridin-4-yl)isophthalic acid], has been synthesized and characterized by elemental analysis, IR spectroscopy, TGA, powder, and single-crystal X-ray diffraction. Structural analysis shows that each PIA(2-) in 1 bridges three Cu(II) ions, and likewise each Cu(II) ion connects to three PIA(2-) ligands, giving a 3-D framework with utp topology and left-/right-handed helical channels. Interestingly, two such identical frameworks interlock with each other to generate a twofold interpenetrated structure that is stabilized by hydrogen bonding and - interactions. In addition, the thermal stability and the magnetic properties of 1 have been investigated. [GRAPHICS]
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收藏
页码：295 / 302
页数：8
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