Photoelectrochemistry and sensor of NO based on a supramolecular system composed of polyhydroquinone and fullerene

被引：12
作者：
Dang, Xueping [1 ,2 ,3 ,4 ,5 ]
Hu, Chengguo [3 ,4 ]
Chen, Huaixia [1 ,2 ]
Huang, Jianlin [1 ,2 ]
Zheng, Dongyun [5 ]
Hu, Shengshui [3 ,4 ]
机构：
[1] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China
[2] Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China
[3] Wuhan Univ, Key Lab Analyt Chem Biol & Med, Minist Educ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
[4] Chinese Acad Sci, State Key Lab Transducer Technol, Beijing 10080, Peoples R China
[5] Hubei Key Lab Med Informat Anal & Tumor Diag Trea, Wuhan 430062, Peoples R China
来源：
SENSORS AND ACTUATORS B-CHEMICAL | 2016年 / 228卷
关键词：
Photoelectrochemistry; Polyhydroquinone (PH(2)Q); Fullerene (C-60); Nitric oxide (NO); Sensor; MOLECULARLY IMPRINTED POLYMER; NITRIC-OXIDE RELEASE; ELECTROCATALYTIC REDUCTION; OXIDATIVE POLYMERIZATION; PHOTOCURRENT GENERATION; CARBON NANOTUBES; FILM; NANOMATERIALS; ELECTRODES; COMPLEXES;
D O I：
10.1016/j.snb.2016.01.103
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
An electron donor-acceptor linked supramolecular system composed of polyhydroquinone (PH(2)Q) and fullerene (C-60) was prepared and characterized by different techniques like TEM, UV-vis, XRD and photo electrochemical photocurrent detection techniques. The photoelectrochemical properties of nitric oxide (NO) were first investigated. An enhanced cathodic photocurrent response was obtained on the PH(2)Q C-60 modified ITO electrode under visible light radiation with NO as electron acceptor. The photoelectrochemical process of NO was discussed and a novel photoelectrochemical sensor of NO was developed. The influence of the main interferents, especially the significant interfering species NO2- was proved to be negligible. The photoelectrochemistry of NO and the new NO sensor may have potential applications in photoelectrochemistry and biological analysis field. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：709 / 715
页数：7
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