Cyclisation of (R)- and (S)-N-allyl-N-(1-phenylethyl) methoxycarbonylacetamide mediated by Mn(III): Preparation and structural assignment of 3-aza-2-oxobicyclo[3.1.0]hexanes

被引：29

作者：

Galeazzi, R ^{[1
]}

Geremia, S ^{[1
]}

Mobbili, G ^{[1
]}

Orena, M ^{[1
]}

机构：

[1] UNIV ANCONA,DIPARTIMENTO SCI MAT & TERRA,I-60131 ANCONA,ITALY

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(96)00466-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(R)- and (S)-N-allyl-N-(I-phenylethyl)methoxycarbonylacetamide, 5 and 6, underwent oxidative cyclisation mediated by Mn(III), to give easily separable diastereomeric mixtures of 3-aza-2-oxobicyclo[3.1.0]hexanes 8a,b and 9a,b, respectively, whose structures were assigned on the basis of H-1 NMR spectra and then confirmed by X-ray diffraction analysis of the derivatives 11b and 14. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：3573 / 3584

页数：12

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