Remarkable transformation of 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene into the 2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienide anion

被引：30

作者：

Cloke, FGN ^{[1
]}

Hitchcock, PB ^{[1
]}

Nixon, JF ^{[1
]}

Wilson, DJ ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 03期

关键词：

D O I：

10.1021/om990885r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In an unprecedented reaction, the reduction of 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene over a potassium mirror in toluene resulted in the abstraction of P3- and generation of the 2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadtenide anion, P2C3Bu3t- (3) The potassium salt of this anion was characterized by an X-ray crystallographic study.

引用

页码：219 / 220

页数：2

共 20 条

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