Viscometric study of dilute poly(acrylonitrile-ammonium itaconate) solutions

被引:2
|
作者
Cui, Chuansheng [1 ]
Wang, Chengguo [1 ]
Jia, Wenjie [1 ]
Zhao, Yaqi [1 ]
机构
[1] Shandong Univ, Coll Mat Sci & Engn, Carbon Fiber Ctr, Jinan 250061, Peoples R China
关键词
ammonium itaconate; dilute solution properties; polyacrylonitrile; viscosity;
D O I
10.1007/s10965-005-9036-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The intrinsic viscosity of dilute poly(acrylonitrile-ammonium itaconate) copolymer solution in dimethyl sulfoxide was studied by viscometry. Abnormal phenomena of the eta(sp)/c versus c curves of poly(acrylonitrile-ammonium itaconate) were found. Owing to the effect of NH4+, there were three anomalistic turning points in the curve of the Huggins dependence compared with other polyacrylonitrile copolymers.
引用
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页码:293 / 296
页数:4
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