Synthesis, Structure and Luminescent Property of a New Zinc(II) Complex

被引：0

作者：

Zhai Ji-Quan ^{[1
,2
]}

Zhang Yu ^{[1
,2
]}

Cheng Jian-Kai ^{[2
]}

Yang Jin-Xia ^{[2
]}

Zhang Xin ^{[2
]}

Qin Ye-Yan ^{[2
]}

Yao Yuan-Gen ^{[1
,2
]}

机构：

[1] Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 34卷 / 10期

关键词：

coordination polymer; hydrogen bonds; pi-pi interactions; topology; luminescent property; COORDINATION POLYMERS; ORGANIC FRAMEWORK; SEMIRIGID LIGAND; METAL-CLUSTERS; EARTH METAL; TRICARBOXYLATE; ARCHITECTURE; LEAD;

D O I：

10.14102/j.cnki.0254-5861.2011-0710

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One new coordination polymer, namely {[Zn(HL)(Hbipy)](2)center dot 3H(2)O}(2) (bipy = 4,4'-bipyridine, H4L = 6-(3',4'-dicarboxyl-phenoxy) isophthalic acid), has been synthesized through a hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectra (IR), and thermogravimetric (TG) analysis. The crystal structure is of monoclinic, space group P2(1)/n with a = 9.6435(3), b = 19.8515(7), c = 12.9731(5) angstrom, beta = 103.023(4)degrees, V = 2419.67(15) angstrom(3), C52H38Zn2N4O21, M-r = 1185.6, Z = 2, D-c = 1.619 g/cm(3), F(000) = 1200, mu = 1.083 mm(-1), the final R = 0.0443 and wR = 0.1079 for 4269 observed reflections (I> 2 sigma(I). The compound features a two-dimensional (2D) framework and stabilizes itself by interlayer pi center dot center dot center dot pi interactions and irmerlayer hydrogen bonds. The 2D layer presents a simple 3-connected 6(3) topology. Moreover, the thermal dynamic stability and luminescent property of the compound have (a)lso been discussed in detail.

引用

页码：1513 / 1518

页数：6

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