Flexible Coordination of Diphosphine Ligands Leading to cis and trans Pd(0), Pd(II), and Rh(I) Complexes

被引：27

作者：

Comanescu, Cezar C. ^{[1
]}

Iluc, Vlad M. ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

INORGANIC CHEMISTRY | 2014年 / 53卷 / 16期

基金：

美国国家科学基金会;

关键词：

METAL-COMPLEXES; C-H; AGOSTIC INTERACTIONS; CHIRAL DIPHOSPHINE; HECK REACTIONS; PALLADIUM; ACTIVATION; CATALYSIS; BACKBONE; PD;

D O I：

10.1021/ic5010566

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of diphosphine ligands (Pr2P)-Pr-i-C6H4-X-C6H4-(PPr2)-Pr-i (for ligand L-1, X = CH2; for ligand L-2, X = CH2CH2) was investigated to determine the preference for cis/trans coordination to palladium(0), palladium(11), and rhodium(I). Increasing the length of the bridging alkyl backbone from one to two carbons changes the geometry of the resulting palladium(II) complexes, with L-1 coordinating preferentially cis, while L-2 coordinates in a trans fashion. Coordination to Pd(0) leads to (LPd)-Pd-1(dba) and (LPd)-Pd-2(dba), in which both ligands accommodate a P-M-P angle close to 120 degrees. L-2 was found to coordinate cis in a rhodium(I) complex ([(LRh)-Rh-2(nbd)][BF4], where nbd = norbornadiene).

引用

页码：8517 / 8528

页数：12

共 50 条

[41] Coordination of resorcin[4]arene-based tetrapyridyl ligands with Pd(II) or Pt(II) complexes.
Zhao, G
Castro, PP
Masangkay, GA
Hernandez, C
Tunstad, LMG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U1501 - U1501
[42] Synthesis, Characterization and Anticancer Studies of Rh(I), Rh(III), Pd(II) and Pt(II) Complexes Bearing A Dithiooxamide Ligand
Askari, Banafshe
Rudbari, Hadi Amiri
Valente, Andreia
Bruno, Giuseppe
Micale, Nicola
Shivalingegowda, Naveen
Krishnappagowda, Lokanath Neratur
CHEMISTRYSELECT, 2020, 5 (02): : 810 - 817
[43] Regioselective control of the thiocarbonylation of terminal acetylenes with arylthiols catalyzed by Pd(II) and diphosphine ligands
El Ali, B
Tijani, J
El-Ghanam, A
Fettouhi, M
TETRAHEDRON LETTERS, 2001, 42 (08) : 1567 - 1570
[44] Cyclodiphosphazanes with hemilabile ponytails: Synthesis, transition metal chemistry (Ru(II), Rh(I), Pd(II), Pt(II)), and crystal and molecular structures of mononuclear (Pd(II), Rh(I)) and Bi- and tetranuclear rhodium(I) complexes
Chandrasekaran, P
Mague, JT
Balakrishna, MS
INORGANIC CHEMISTRY, 2005, 44 (22) : 7925 - 7932
[45] Tridentate Assembling Ligands Based on Oxazoline and Phosphorus Donors in Dinuclear Pd(I)-Pd(I) Complexes
Zhang, Jing
Pattacini, Roberto
Braunstein, Pierre
INORGANIC CHEMISTRY, 2009, 48 (24) : 11954 - 11962
[46] Multisite polypyridyl ligands as platforms for the synthesis of Rh/Zn, Rh/Pd, and Rh/Pt heterometallic complexes
Goforth, Sarah K.
Walroth, Richard C.
McElwee-White, Lisa
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
[47] COMPLEXES OF PD(I) AND PD(0) IN THE CATALYSIS OF THE OXIDATIVE ACETOXYLATION OF TOLUENE IN BENZYL ACETATE
STARCHEVSKII, MK
VARGAFTIK, MN
MOISEEV, II
KINETICS AND CATALYSIS, 1980, 21 (06) : 1035 - 1041
[48] Unusual coordination preferences of flexible tetradentate ligands and thiocyanate anions leads to trans nickel(II) and cis manganese(II) compounds
Karmakar, Tapan K.
Ghosh, Barindra K.
Usman, A.
Fun, Hoon-Kun
Chandra, Swapan K.
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2006, 45 (06): : 1356 - 1361
[49] Coordination chemistry of Pd(II) complexes with P-donor ligands - An introduction to synthesis and structural characterization in coordination chemistry
Urriolabeitia, EP
JOURNAL OF CHEMICAL EDUCATION, 1997, 74 (03) : 325 - 327
[50] A comparison of MOP-phosphonite ligands and their applications in Rh(I)- and Pd(II)-catalysed asymmetric transformations
Fleming, James T.
Wills, Corinne
Waddell, Paul G.
Harrington, Ross W.
Higham, Lee J.
DALTON TRANSACTIONS, 2016, 45 (39) : 15660 - 15670

← 1 2 3 4 5 →