Three transition-metal polymers from imidazole dicarboxylates-bearing methoxyphenyl groups: syntheses, crystal structures and properties

被引：9

作者：

Xiong, Zhifang ^{[1
]}

Yuan, Pengfei ^{[1
]}

Xie, Zhengkun ^{[1
]}

Li, Gang ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China

来源：

SUPRAMOLECULAR CHEMISTRY | 2014年 / 26卷 / 5-6期

基金：

中国国家自然科学基金;

关键词：

transition-metal polymers; imidazole dicarboxylate; structure; property; ORGANIC FRAMEWORK MATERIALS; SECONDARY BUILDING UNITS; MAGNETIC-PROPERTIES; COORDINATION; COMPLEXES; SERIES; 2-PROPYL-4,5-DICARBOXYLATE-IMIDAZOLE; DIVERSITY; TEMPLATE; NETWORK;

D O I：

10.1080/10610278.2013.842238

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three coordination polymers, namely, {[Cu-2(HMOPhIDC)(4,4-bipy)]}(n) (H3MOPhIDC=2-(3-methoxyphenyl)-1H-imidazole-4,5-dicarboxylic acid) (1), [Co(HDMOPhIDC)(phen)](n) (H3DMOPhIDC=2-(3,4-dimethoxyphenyl)-1H-imidazole-4,5-dicarboxylic acid) (2) and [Ni-2(HDMOPhIDC)(2)(H2O)(4)](n) (3) have been prepared under hydrothermal condition and characterised by elemental analyses, infrared spectroscopy and single-crystal X-ray diffraction. Each of the polymers 1-3 is a 1D column-like structure and displays a 3D supramolecular network via the ... stacking or hydrogen bond interactions. Furthermore, fluorescence and UV-vis spectroscopic properties of the polymers have been studied.

引用

页码：346 / 357

页数：12

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