Influence of exfoliated graphene nanoplatelets on flame retardancy of kenaf flour polypropylene hybrid nanocomposites

被引:98
作者
Idumah, Christopher Igwe [1 ,2 ]
Hassan, Azman [1 ]
Bourbigot, Serge [3 ]
机构
[1] Univ Teknol Malaysia, Fac Chem Engn, Dept Polymer Engn, Enhanced Polymer Res Grp EnPRO, Skudai 81310, Johor Darul Tak, Malaysia
[2] Ebonyi State Univ, Azuiyi Udene, Abakaliki, Nigeria
[3] ENSCL, Res Grp, Fire Unite Mat & Transformat UMET, Villeneuve Dascq, France
关键词
Polypropylene kenaf composite; Graphene nanoplatelets; Non-halogen flame retardants; MECHANICAL-PROPERTIES; THERMAL-OXIDATION; MULTILAYER GRAPHENE; FIRE RETARDANCY; COMPOSITES; FLAMMABILITY; POLYMERS; STYRENE; METHACRYLATE; PERFORMANCE;
D O I
10.1016/j.jaap.2017.01.006
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this study, we report influence of exfoliated graphene nanoplatelets on the flame retardancy and thermal properties of hybrid kenaf flour graphene nanoplatelets polypropylene nanocomposites. Mass loss calorimeter, Limiting oxygen index and Universal laboratories-94-V fire test instruments were employed for flammability investigations. Fire results revealed improved flame retardancy of composites through enhanced fire performance index, prolonged time to ignition and reduced fire growth index. Heat release rate, peak heat release rate, time to peak heat release rate, mass loss rate and total heat release rate essential for the protection of human lives and properties during actual fire scenario were enhanced. Incorporation of graphene nanoplatelets improved flame retardancy of the materials. The GNP char structure improved flame retardancy by acting as heat shield and protective layering on surface of the materials thereby hindering transfer of oxygen and heat from the fire region to the underlying matrix while simultaneously inhibiting the penetration of flammable gases from underlying matrix to the combustion zone thereby cutting-off the fire track. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:65 / 72
页数:8
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