Nitrite complexes of the rare earth elements

被引：8

作者：

Pouessel, Jacky ^{[1
]}

Thuery, Pierre ^{[1
]}

Berthet, Jean-Claude ^{[1
]}

Cantat, Thibault ^{[1
]}

机构：

[1] CEA Saclay, CNRS UMR 3299, SIS2M, CEA,IRAMIS, F-91191 Gif Sur Yvette, France

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 11期

关键词：

ACID SOLUTIONS; CRYSTAL-STRUCTURE; EXTRACTION; LANTHANIDES; YTTRIUM; URANIUM; ION;

D O I：

10.1039/c3dt52703d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination chemistry of the nitrite anion has been investigated with rare earth elements, and the resulting complexes were structurally characterized. Among them, the first homoleptic examples of nitrite complexes of samarium, ytterbium and yttrium are described. The coordination behavior of the nitrite ion is directly controlled by the ionic radius of the metal cation. While the nitrito ligand is stable in the coordination sphere of cerium(III), it is readily reduced by SmI2.

引用

页码：4415 / 4425

页数：11

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