A thorough investigation of the synthetic problems of vic-bis-hydroxylamine -: the precursor of Ullman's nitroxides

被引：43
作者：
Ovcharenko, V [1 ]
Fokin, S
Rey, P
机构：
[1] Int Tomog Ctr, Novosibirsk 630090, Russia
[2] CEA, Dept Rech Fondamentale & Mat Condensee, Serv Chim Inorgan & Biol, Lab Chim Coordinat,CNRS,URA 1194, F-38041 Grenoble, France
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1999年 / 334卷
关键词：
hydroxylamine derivatives; nitroxides;
D O I：
10.1080/10587259908023308
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The products formed in the course of the reduction of 2,3-dimethyl-2,3-dinitrobutane to 2,3-dihydroxylamino-2,3-dimethylbutane in a Zn/NH4Cl/EtOH-H2O system have been investigated. An improved synthesis of 2,3-dihydroxylamino-2,3-dimethylbutane (and its monosulphate salt) - the key precursor of Ullman's nitroxides - in a Zn/NH4Cl/THF-H2O system is proposed.
引用
收藏
页码：109 / 119
页数：11
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