Solid electrolyte Sm0.2Ce0.8O2-δ reinforced polymer composite membranes for high temperature proton exchange membrane fuel cells

被引:1
作者
Niu, Bingbing [1 ]
Yi, Wendi [1 ]
Liang, Jiantao [1 ]
Guo, Shuang [1 ]
Xu, Baomin [1 ]
机构
[1] Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China
关键词
HT-PEMFCs; Nanoparticles; Polymeric composites; Long-term stability;
D O I
10.1016/j.matlet.2020.129241
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We designed a new type of high temperature proton exchange membrane (HT-PEM), which consists of polyethersulfone (PES)-Polyvinylpyrrolidone (PVP)-xSm(0.2)Ce(0.8)O(1.9) (SDC) (x = 0, 2 wt%, 4 wt%, 6 wt%), and the effect of SDC contents was systematically studied. The incorporation of SDC nanoparticles into the membrane plays a very important role in compromising the conductivity, the mechanical strength, and the durability of the membrane, because SDC has a certain extent proton conductivity, and the SDC has flocculent structure. The single cell shows the maximum power density of 1229 mW/cm(2) under a backpressure of 0.15 MPa at 160 degrees C, and the output performance keeps stable during the 1000 h stability test at a constant voltage of 0.7 V. (C) 2020 Elsevier B.V. All rights reserved.
引用
收藏
页数:4
相关论文
共 17 条
[1]   THE GROTTHUSS MECHANISM [J].
AGMON, N .
CHEMICAL PHYSICS LETTERS, 1995, 244 (5-6) :456-462
[2]   Imidazole microcapsules toward enhanced phosphoric acid loading of polymer electrolyte membrane for anhydrous proton conduction [J].
Dang, Jingchuan ;
Zhao, Liping ;
Zhang, Jie ;
Liu, Jindun ;
Wang, Jingtao .
JOURNAL OF MEMBRANE SCIENCE, 2018, 545 :88-98
[3]   Polybenzimidazole/SiO2 hybrid membranes for high temperature proton exchange membrane fuel cells [J].
Devrim, Yilser ;
Devrim, Huseyin ;
Eroglu, Inci .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (23) :10044-10052
[4]   A SmBaCo2O5+&DELTA double perovskite with epitaxially grown Sm0.2Ce0.8O2-δ nanoparticles as a promising cathode for solid oxide fuel cells [J].
Du, Zhihong ;
Li, Keyun ;
Zhao, Hailei ;
Dong, Xu ;
Zhang, Yang ;
Swierczek, Konrad .
JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (28) :14162-14170
[5]   Submicro-pore containing poly(ether sulfones)/polyvinylpyrrolidone membranes for high-temperature fuel cell applications [J].
Guo, Zhibin ;
Xiu, Ruijie ;
Lu, Shanfu ;
Xu, Xin ;
Yang, Shichun ;
Xiang, Yan .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (16) :8847-8854
[6]  
Hideaki I., 1996, SOLID STATE IONICS, V83, P1
[7]   Unprecedented room-temperature electrical power generation using nanoscale fluorite-structured oxide electrolytes [J].
Kim, Sangtae ;
Anselmi-Tambtirini, Umberto ;
Park, Hee Jung ;
Martin, Manfred ;
Munir, Zuhair A. .
ADVANCED MATERIALS, 2008, 20 (03) :556-+
[8]   High temperature anhydrous proton exchange membranes based on chemically-functionalized titanium/polybenzimidazole composites for fuel cells [J].
Lee, Sangrae ;
Seo, Kwangwon ;
Ghorpade, Ravindra, V ;
Nam, Ki-Ho ;
Han, Haksoo .
MATERIALS LETTERS, 2020, 263
[9]   A high conductivity Cs2.5H0.5PMo12O40/polybenzimidazole (PBI)/H3PO4 composite membrane for proton-exchange membrane fuel cells OPE-rating at high temperature [J].
Li, Ming-Qiang ;
Shao, Zhi-Gang ;
Scott, Keith .
JOURNAL OF POWER SOURCES, 2008, 183 (01) :69-75
[10]   High temperature proton exchange membranes based on polybenzimidazoles for fuel cells [J].
Li, Qingfeng ;
Jensen, Jens Oluf ;
Savinell, Robert F. ;
Bjerrum, Niels J. .
PROGRESS IN POLYMER SCIENCE, 2009, 34 (05) :449-477