Ultrasound promoted rapid and green synthesis of 1,8-dioxo-octahydroxanthenes derivatives using nanosized MCM-41-SO3H as a nanoreactor, nanocatalyst in aqueous media

被引：98
作者：
Rostamizadeh, Shahnaz [1 ]
Amani, Ali Mohammad [1 ]
Mahdavinia, Gholam Hossein [3 ]
Amiri, Gelareh [1 ]
Sepehrian, Hamid [2 ]
机构：
[1] KN Toosi Univ Technol, Dept Chem, Tehran, Iran
[2] AEOI, Nucl Sci & Technol Res Inst, Jaber Ibn Hayan Res Labs, Tehran, Iran
[3] Islamic Azad Univ, Dept Chem, Marvdasht Branch, Marvdasht, Iran
来源：
ULTRASONICS SONOCHEMISTRY | 2010年 / 17卷 / 02期
关键词：
Ultrasonic irradiation; Green chemistry; Nanocatalyst; MCM-41-SO3H; 1,8-Dioxo-octahydroxanthenes; MOLECULAR-SIEVES; 5,5-DIMETHYL-1,3-CYCLOHEXANEDIONE; CONDENSATION; STABILITY; ALDEHYDES; CATALYST;
D O I：
10.1016/j.ultsonch.2009.10.004
中图分类号：
O42 [声学];
学科分类号：
070206 ; 082403 ;
摘要：
An efficient and green procedure has been developed for the synthesis of 1,8-dioxo-octahydroxanthenes derivatives. The reaction was carried out in water under ultrasound irradiation, using nanosized MCM-41-SO3H. In this method, several types of aromatic aldehyde, containing electron-withdrawing groups as well as electron-donating groups, were rapidly converted to the corresponding 1,8-dioxo-octahydroxanthenes in good to excellent yields. This novel synthetic method is especially favored because it provides a synergy of the nanosized MCM-41-SO3H and ultrasound irradiation which offers the advantages of high yields, short reaction times, simplicity and easy workup compared to the conventional methods reported in the literature. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：306 / 309
页数：4
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