A novel ferrocene-based thiacalix[4]arene ditopic receptor for electrochemical sensing of europium(III) and dihydrogen phosphate ions

被引：50
作者：
Guo, Dian-Shun [1 ]
Liu, Zhi-Peng [1 ]
Ma, Jian-Ping [1 ]
Huang, Ru-Qi [1 ]
机构：
[1] Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China
来源：
TETRAHEDRON LETTERS | 2007年 / 48卷 / 07期
基金：
中国国家自然科学基金;
关键词：
thiacalix[4]arene; ferrocene; redox-active ditopic receptor; electrochemical recognition; sensor;
D O I：
10.1016/j.tetlet.2006.12.047
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We have synthesized a ferrocene-based 1,3-alternate thiacalix[4]arene ditopic receptor 3 that contains four identical polyether arms terminated with the ferrocene amide moieties. Our studies have revealed that this redox-active receptor can be used as an electrochemical sensor to recognize both europium (Eu3+) and clihydrogen phosphate (H2PO4-) ions with a high selectivity. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1221 / 1224
页数：4
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