Degradation of methyl orange by ozone in the presence of ferrous and persulfate ions in a rotating packed bed

This work investigated the degradation of methyl orange by ozone in the presence of ferrous and per sulfate ions (O-3/Fe2+/S2O82-) in a rotating packed bed. The effects of various operating parameters such as initial pH, rotational speed, gas-liquid ratio, ozone inlet concentration and reaction temperature on the degradation rate of methyl orange were studied with an aim to optimize the operation conditions. Results reveal that the degradation rate increased with an increase in rotational speed, gas liquid ratio and ozone inlet concentration, and reached a maximum at 25 degrees C and initial pH 4. Contrast experiments involving ozone and ferrous ions (O-3/Fe2+) were also carried out, and the results show approximately 10% higher degradation rate and COD removal in the O-3/Fe2+/S2O82- process than in the O-3/Fe2+ process. Additionally, the intermediates of the degradation process were analyzed to ascertain the degradation products. (C) 2015 Elsevier Ltd. All rights reserved.