Highly sensitive detection of Hg2+ using ruthenium complex-based probe in water

被引：1

作者：

Wu, Yuhao ^{[1
,2
]}

Du, Kang ^{[1
,2
]}

Xu, Ce ^{[1
,2
]}

Li, Xianghong ^{[1
,2
]}

Tang, Dingguo ^{[1
,2
]}

机构：

[1] South Cent Univ Nationalities, Minist Educ, Key Lab Catalysis & Energy Mat Chem, Wuhan 430074, Peoples R China

[2] South Cent Univ Nationalities, Hubei Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2021年 / 935卷

基金：

美国国家科学基金会;

关键词：

Cyclometalated ruthenium complex; Mercury ions; Mesoporous silica nanoparticles; IRIDIUM(III) COMPLEX; SELECTIVE DETECTION; MERCURY; FLUORESCENT; DESIGN; SENSOR; IONS;

D O I：

10.1016/j.jorganchem.2021.121690

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new ruthenium complex using 2-(2-thienyl)pyridine as cyclometalating ligand and 2,2'-bipyridine-5,5'dicarboxylic acid as anchoring ligands was successfully synthesized and used as an Hg2+ colorimetric probe. Upon adding Hg2+ into the aqueous solution of the complex, a significant absorption spectral change with a blue shift of 142 nm can be observed accompanied by an obvious color change. The detection limit of Hg2+ was calculated to be as low as 4.7 x 10(-8) M in neutral aqueous medium by using UV-Vis absorption technology. Then, it was loaded onto mesoporous silica nanoparticles, which was characterized by TEM, XPS and TG. The new composite material Ru-COOH@NH2-MSNs displayed abilities to enrich and separate Hg2+ in water, which demonstrates a potential application in environmental system. (C) 2021 Elsevier B.V. All rights reserved.

引用

页数：8

共 46 条

[41] A highly sensitive colorimetric and ratiometric fluorescent probe based on 3-hydroxyphthalimide for detection of Hg2+ in aqueous solution and its application in real sample analysis [J].

Yang, Binying ;

Huang, Jing ;

Bao, Cheng ;

Zhang, Shishen ;

Han, Yifeng .

TETRAHEDRON LETTERS, 2020, 61 (09)

[42] A simple approach to prepare monodisperse mesoporous silica nanospheres with adjustable sizes [J].

Yu, Meihua ;

Zhou, Liang ;

Zhang, Jun ;

Yuan, Pei ;

Thorn, Peter ;

Gu, Wenyi ;

Yu, Chengzhong .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 376 :67-75

[43] Dinuclear HgII tetracarbene complex-triggered aggregation-induced emission for rapid and selective sensing of Hg2+ and organomercury species [J].

Yuan, Bin ;

Wang, Dong-Xia ;

Zhu, Li-Na ;

Lan, Yan-Long ;

Cheng, Meng ;

Zhang, Li-Ming ;

Chu, Jun-Qing ;

Li, Xiao-Zeng ;

Kong, De-Ming .

CHEMICAL SCIENCE, 2019, 10 (15) :4220-4226

[44] The development of anticancer ruthenium(II) complexes: from single molecule compounds to nanomaterials [J].

Zeng, Leli ;

Gupta, Pranav ;

Chen, Yanglu ;

Wang, Enju ;

Ji, Liangnian ;

Chao, Hui ;

Chen, Zhe-Sheng .

CHEMICAL SOCIETY REVIEWS, 2017, 46 (19) :5771-5804

[45]

Zhang X., 2008, ANGEW CHEM, V120, P8145, DOI [10.1002/ange.200803246, DOI 10.1002/ANGE.200803246]

[46] Organometallic acetylides of PtII, AuI and HgII as new generation optical power limiting materials [J].

Zhou, Gui-Jiang ;

Wong, Wai-Yeung .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (05) :2541-2566

← 1 2 3 4 5 →