Solid-state NMR studies of methanol-to-aromatics reaction over silver exchanged HZSM-5 zeolite

被引：33
|
作者：
Zeng, Danfin [1 ]
Yang, Jun [1 ]
Wang, Jiqing [1 ]
Xu, Jun [1 ]
Yang, Yongxia [1 ]
Ye, Chaohui [1 ]
Deng, Feng [1 ]
机构：
[1] Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
来源：
MICROPOROUS AND MESOPOROUS MATERIALS | 2007年 / 98卷 / 1-3期
基金：
中国国家自然科学基金;
关键词：
methanol conversion to aromatics; AgZSM-5; solid-state NMR;
D O I：
10.1016/j.micromeso.2006.09.012
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Solid-state NMR spectroscopy was used to study the conversion of methanol to aromatics (MTA) over silver exchanged HZSM-5 zeolites. It is the silver oxide rather than silver cation that plays a crucial role for the MTA reaction. The aromatic products (mainly toluene and benzene) are formed at the expense of the small alkanes (mainly propane and isobutane). AgZSM-5 zeolite calcined in air shows much higher activity and selectivity for the MTA conversion compared with AgZSM-5 zeolite calcined in vacuum or HZSM-5 zeolite. A possible reaction mechanism is proposed for the MTA conversion on the AgZSM-5 zeolite. (C) 2006 Elsevier Inc. All rights reserved.
引用
收藏
页码：214 / 219
页数：6
相关论文
共 50 条
  • [11] Study on the effect of methanol on the transformation reaction of thiophene over HZSM-5 zeolite
    Pan, Peng
    Luo, Liwen
    Li, Hu
    Yu, Huizheng
    Xia, Daohong
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [12] The joint reaction of methanol and i-butane over the HZSM-5 zeolite
    Roohollahi, Gholamreza
    Kazemeini, Mohammad
    Mohammadrezaee, Alireza
    Golhosseini, Reza
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2013, 19 (03) : 915 - 919
  • [13] Study on the reaction performance of methanol to aromatics over Zn/HZSM-5 catalysts with alumina
    Ji, Hong-Qiang
    Zhang, Qiang
    Chen, Lu
    Shan, Hong-Hong
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2014, 42 (11): : 1387 - 1393
  • [14] Influence of preparation method on the performance of Zn-containing HZSM-5 catalysts in methanol-to-aromatics
    Niu, Xianjun
    Gao, Jie
    Miao, Qing
    Dong, Mei
    Wang, Guofu
    Fan, Weibin
    Qin, Zhangfeng
    Wang, Jianguo
    MICROPOROUS AND MESOPOROUS MATERIALS, 2014, 197 : 252 - 261
  • [15] A high-resolution solid-state NMR study on nano-structured HZSM-5 zeolite
    Zhang, WP
    Bao, XH
    Guo, XW
    Wang, XS
    CATALYSIS LETTERS, 1999, 60 (1-2) : 89 - 94
  • [16] Solid state 13C NMR studies of methane dehydroaromatization reaction on Mo/HZSM-5 and W/HZSM-5 catalysts
    Yang, J
    Ma, D
    Deng, F
    Luo, Q
    Zhang, MJ
    Bao, XH
    Ye, CH
    CHEMICAL COMMUNICATIONS, 2002, (24) : 3046 - 3047
  • [17] Catalytic performance of imidazole modified HZSM-5 for methanol to aromatics reaction
    Tian, Haifeng
    Zhang, Zhuangzhuang
    Chang, Hui
    Ma, Xiaoxun
    JOURNAL OF ENERGY CHEMISTRY, 2017, 26 (03) : 574 - 583
  • [18] Catalytic performance of imidazole modified HZSM-5 for methanol to aromatics reaction
    Haifeng Tian
    Zhuangzhuang Zhang
    Hui Chang
    Xiaoxun Ma
    JournalofEnergyChemistry, 2017, 26 (03) : 574 - 583
  • [19] Study on methylation of phenol with methanol over HZSM-5 zeolite
    Zhang, K
    Xiang, SH
    Zhang, HB
    Liu, SY
    Li, HX
    CHINESE JOURNAL OF CATALYSIS, 2001, 22 (06) : 545 - 549
  • [20] Unusual deactivation of HZSM-5 zeolite in the methanol to hydrocarbon reaction
    Qi, Liang
    Li, Jinzhe
    Wang, Linying
    Xu, Lei
    Liu, Zhongmin
    CATALYSIS SCIENCE & TECHNOLOGY, 2017, 7 (04) : 894 - 901
12345