Ammonium citrate derived carbon quantum dot as on-off-on fluorescent sensor for detection of chromium(VI) and sulfites

被引:42
作者
Fang, Liyang [1 ]
Zhang, Lu [1 ]
Chen, Zhenzhen [1 ]
Zhu, Chaosheng [1 ]
Liu, Juanjuan [1 ]
Zheng, Jingtang [1 ,2 ]
机构
[1] China Univ Petr, Sch Chem Engn, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China
[2] Fudan Univ, State Key Lab Mol Engn Polymers, Shanghai, Peoples R China
基金
中国国家自然科学基金;
关键词
Ammonium citrate derived C-dots; On-off-on fluorescent probe; Electron exchange quenching; The detections of Cr(VI) and sulfites;
D O I
10.1016/j.matlet.2016.12.098
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The ammonium citrate derived carbon quantum dot (C-dots) with strong fluorescence and high photostability were synthesized via one-step hydrothermal approach. Based on fluorescence quenching and fluorescence recovery of C-dots, the as-prepared C-dots were innovatively developed as an effective on-off-on fluorescent probe for selective and sensitive detection of Cr(VI) and sulfites with detection limit 0.01 mu mol/L and 0.35 mu mol/L, respectively. It is found that mechanism of fluorescence quenching of the as-prepared C-dots by Cr(VI) can be mainly attributed to a kind of electron exchange quenching. (C) 2016 Published by Elsevier B.V.
引用
收藏
页码:1 / 4
页数:4
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