Selective intercalation of o-phenylene diamine into molybdenum oxide layers

被引：3

作者：

Shao, Ke ^{[1
]}

Cao, Hui Qun ^{[1
]}

Qiu, Qi ^{[1
]}

机构：

[1] Shenzhen Univ, Coll Chem & Chem Engn, Shenzhen 518060, Peoples R China

来源：

MATERIALS RESEARCH BULLETIN | 2009年 / 44卷 / 03期

关键词：

Composites; Layered compounds; Intercalation reactions; DOUBLE HYDROXIDE; POLYMERIZATION; INSERTION; PROPERTY; GLYCOL;

D O I：

10.1016/j.materresbull.2008.06.013

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

o-Phenylene diamine molecules were intercalated into molybdenum oxide layers by an in situ co-precipitation method. The structure and composition of the intercalated material were studied by X-ray diffraction (XRD), infrared spectroscopy (IR) and elemental analysis. XRD data evidenced a layered structure with a spacing of 18 angstrom, which corresponds to an organic-inorganic hybrid-layered structure. IR and UV-vis spectra indicated the polymerization of o-phenylene between the molybdenum oxide layers. It was also observed that compared with aniline molecules, o-phenylene diamine molecules can be selectively intercalated into molybdenum oxide layers. We provide evidence that affinity for o-phenylene diamine to form intermolecular polymers is the reason for its selective intercalation. The polymer chain structure of o-phenylene diamine makes it a preferential guest species compared with aniline. We believe that this opens a new way to create organic-inorganic hybrid structures. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：678 / 681

页数：4

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