Nitrogen doped TiO2/Graphene nanofibers as DSSCs photoanode

被引:29
作者
Gao, Ningxiao [1 ]
Wan, Tingting [1 ]
Xu, Zhiyang [2 ]
Ma, Liansheng [1 ]
Ramakrishna, Seeram [3 ]
Liu, Yong [2 ]
机构
[1] Beijing Univ Chem Technol, Coll Mech & Elect Engn, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Beijing Key Lab Adv Funct Polymer Composites, Coll Mat Sci & Engn, Beijing 100029, Peoples R China
[3] Natl Univ Singapore, Ctr Nanofibers & Nanotechnol, Singapore 1157, Singapore
基金
中国国家自然科学基金;
关键词
Dye-sensitized solar cell; Electrospinning; Hydrothermal method; Semiconductors; SENSITIZED SOLAR-CELLS; TIO2; PERFORMANCE; EFFICIENCY; COMPOSITES; COLLECTION; ELECTRODES;
D O I
10.1016/j.matchemphys.2020.123542
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Photoanode optimization of the dye-sensitized solar cell is a crucial part of its performance improvement. In this study, graphene-containing TiO2 nanofibers were prepared by electrospinning, and the nitrogen element was doped via the hydrothermal method. After that, a nitrogen-graphene co-doped TiO2 nanofiber photoanode was prepared using a doctor blade coating process. Micromorphological characterization revealed that nitrogen and graphene were successfully doped into composite nanofibers with favorable morphology and distribution. Ultraviolet-visible light spectroscopy and monochromatic light conversion efficiency data demonstrated that the doping of nitrogen enhanced the cell's response to sunlight. The J-V curve was obtained under solar simulation, and the conversion efficiency of 5.01% was reached, which was 26% higher than that of undoped. Therefore, the co-doped composite fiber makes a promising prospect for further applications.
引用
收藏
页数:8
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